dc.contributor.author | Lemes, Maykon A. | |
dc.contributor.author | Mavragani, Niki | |
dc.contributor.author | Richardson, Paul | |
dc.contributor.author | Zhang, Yixin | |
dc.contributor.author | Gabidullin, Bulat | |
dc.contributor.author | Brusso, Jaclyn L. | |
dc.contributor.author | Moilanen, Jani O. | |
dc.contributor.author | Murugesu, Muralee | |
dc.date.accessioned | 2023-12-14T08:18:47Z | |
dc.date.available | 2023-12-14T08:18:47Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Lemes, M. A., Mavragani, N., Richardson, P., Zhang, Y., Gabidullin, B., Brusso, J. L., Moilanen, J. O., & Murugesu, M. (2020). Unprecedented intramolecular pancake bonding in a {Dy2} single-molecule magnet. <i>Inorganic Chemistry Frontiers</i>, <i>7</i>(14), 2592-2601. <a href="https://doi.org/10.1039/D0QI00365D" target="_blank">https://doi.org/10.1039/D0QI00365D</a> | |
dc.identifier.other | CONVID_35316162 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/92331 | |
dc.description.abstract | The first example of unique coordination induced intramolecular pancake bonding was achieved through the reduction of two bis(pyrazolyl)-tetrazine ligands, affording [MIII 2 (μ-(bpytz)2)(THMD)4](M = Dy, Y; bpytz = 3,6-bis(3,5-dimethyl-pyrazolyl)-1,2,4,5-tetrazine; TMHD = 2,2,6,6-tetramethyl-3,5-heptanedionate). To provide a cohesive magneto-structural correlation, the mono bis(pyrazolyl)-tetrazine bridged congener [DyIII 2 (μ-bpytz)(THMD)6]·4(C6H6) was also isolated. Both metal complexes exhibit single-molecule magnet behaviour under an applied dc field. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.relation.ispartofseries | Inorganic Chemistry Frontiers | |
dc.rights | In Copyright | |
dc.title | Unprecedented intramolecular pancake bonding in a {Dy2} single-molecule magnet | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202312148321 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 2592-2601 | |
dc.relation.issn | 2052-1545 | |
dc.relation.numberinseries | 14 | |
dc.relation.volume | 7 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © the Partner Organisations 2020 | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 315829 | |
dc.relation.grantnumber | 320015 | |
dc.subject.yso | magneettiset ominaisuudet | |
dc.subject.yso | kompleksiyhdisteet | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p597 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
dc.relation.doi | 10.1039/D0QI00365D | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
jyx.fundingprogram | Academy Research Fellow, AoF | en |
jyx.fundingprogram | Research costs of Academy Research Fellow, AoF | en |
jyx.fundingprogram | Akatemiatutkija, SA | fi |
jyx.fundingprogram | Akatemiatutkijan tutkimuskulut, SA | fi |
jyx.fundinginformation | We thank the University of Ottawa, the CFI, the NSERC and the Academy of Finland (projects 315829, 320015) for their financial support. M. A. L. thanks Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPQ; 201395/2014-6) for a PhD scholarship. CSC-IT Centre for Science in Finland, the Finnish Grid and Cloud Infrastructure (persistent identifier urn:nbn:fi:research-infras-2016072533) and Prof. H. M. Tuononen (University of Jyväskylä) are acknowledged for providing computational resources for the project. | |
dc.type.okm | A1 | |