Metal–Organic Nanocapsules with Functionalized s-Heptazine Ligands
| dc.contributor.author | Maxwell, Lindley | |
| dc.contributor.author | Martínez, Héctor | |
| dc.contributor.author | Martín-Rodríguez, Alejandro | |
| dc.contributor.author | Gómez-Coca, Silvia | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Ruiz, Eliseo | |
| dc.date.accessioned | 2023-01-19T12:56:28Z | |
| dc.date.available | 2023-01-19T12:56:28Z | |
| dc.date.issued | 2021 | |
| dc.identifier.citation | Maxwell, L., Martínez, H., Martín-Rodríguez, A., Gómez-Coca, S., Rissanen, K., & Ruiz, E. (2021). Metal–Organic Nanocapsules with Functionalized s-Heptazine Ligands. <i>Inorganic Chemistry</i>, <i>60</i>(2), 570-573. <a href="https://doi.org/10.1021/acs.inorgchem.0c03631" target="_blank">https://doi.org/10.1021/acs.inorgchem.0c03631</a> | |
| dc.identifier.other | CONVID_47615900 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/85108 | |
| dc.description.abstract | A metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society | |
| dc.relation.ispartofseries | Inorganic Chemistry | |
| dc.rights | In Copyright | |
| dc.title | Metal–Organic Nanocapsules with Functionalized s-Heptazine Ligands | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202301191408 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Orgaaninen kemia | fi |
| dc.contributor.oppiaine | Organic Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 570-573 | |
| dc.relation.issn | 0020-1669 | |
| dc.relation.numberinseries | 2 | |
| dc.relation.volume | 60 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2020 American Chemical Society | |
| dc.rights.accesslevel | openAccess | fi |
| dc.subject.yso | nanohiukkaset | |
| dc.subject.yso | supramolekulaarinen kemia | |
| dc.subject.yso | organometalliyhdisteet | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p23451 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p37759 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p28123 | |
| dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
| dc.relation.doi | 10.1021/acs.inorgchem.0c03631 | |
| jyx.fundinginformation | This work had financial support by the Ministerio de Ciencia e Innovación through Grants PGC2018-093863-B-C21 and MDM-2017-0767 and by the Generalitat de Catalunya through Grant SGR2017-1289. E.R. thanks the Generalitat de Catalunya for his ICREA Academia grant. L.M. thanks Conicyt-Chile for a predoctoral fellowship. S.G.-C. thanks the Generalitat de Catalunya for a Beatriu de Pinós Fellowship (2017 BP 00080). | |
| dc.type.okm | A1 |
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