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dc.contributor.authorMaxwell, Lindley
dc.contributor.authorMartínez, Héctor
dc.contributor.authorMartín-Rodríguez, Alejandro
dc.contributor.authorGómez-Coca, Silvia
dc.contributor.authorRissanen, Kari
dc.contributor.authorRuiz, Eliseo
dc.date.accessioned2023-01-19T12:56:28Z
dc.date.available2023-01-19T12:56:28Z
dc.date.issued2021
dc.identifier.citationMaxwell, L., Martínez, H., Martín-Rodríguez, A., Gómez-Coca, S., Rissanen, K., & Ruiz, E. (2021). Metal–Organic Nanocapsules with Functionalized s-Heptazine Ligands. <i>Inorganic Chemistry</i>, <i>60</i>(2), 570-573. <a href="https://doi.org/10.1021/acs.inorgchem.0c03631" target="_blank">https://doi.org/10.1021/acs.inorgchem.0c03631</a>
dc.identifier.otherCONVID_47615900
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/85108
dc.description.abstractA metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesInorganic Chemistry
dc.rightsIn Copyright
dc.titleMetal–Organic Nanocapsules with Functionalized s-Heptazine Ligands
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202301191408
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange570-573
dc.relation.issn0020-1669
dc.relation.numberinseries2
dc.relation.volume60
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 American Chemical Society
dc.rights.accesslevelopenAccessfi
dc.subject.ysonanohiukkaset
dc.subject.ysosupramolekulaarinen kemia
dc.subject.ysoorganometalliyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p23451
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1021/acs.inorgchem.0c03631
jyx.fundinginformationThis work had financial support by the Ministerio de Ciencia e Innovación through Grants PGC2018-093863-B-C21 and MDM-2017-0767 and by the Generalitat de Catalunya through Grant SGR2017-1289. E.R. thanks the Generalitat de Catalunya for his ICREA Academia grant. L.M. thanks Conicyt-Chile for a predoctoral fellowship. S.G.-C. thanks the Generalitat de Catalunya for a Beatriu de Pinós Fellowship (2017 BP 00080).
dc.type.okmA1


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