Self-assembly of M4L4 tetrahedral cages incorporating pendant P=S and P=Se functionalised ligands
Butler, P. W. V., Kruger, P. E., & Ward, J. S. (2019). Self-assembly of M4L4 tetrahedral cages incorporating pendant P=S and P=Se functionalised ligands. Chemical Communications, 55(69), 10304-10307. https://doi.org/10.1039/C9CC05443J
Published inChemical Communications
© The Royal Society of Chemistry, 2019
Herein, the synthesis of metal–organic tetrahedral cages featuring flexible thio- and selenophosphate-based ligands is described. The cages were prepared by sub-component self-assembly of A=P(OC6H4NH2-4)3 (A = S, Se) or S=P(SC6H4NH2-4)3,2-pyridinecarboxaldehyde, and either Fe[BF4]2 or Co[BF4]2. Preliminary host–guest studies into the ability of the pendant PQS and PQSe groups to interact with suitable substrates will be discussed.
PublisherRoyal Society of Chemistry
Publication in research information system
MetadataShow full item record
Showing items with similar title or keywords.
Hyper-CEST NMR of metal organic polyhedral cages reveals hidden diastereomers with diverse guest exchange kinetics Jayapaul, Jabadurai; Komulainen, Sanna; Zhivonitko, Vladimir V.; Mareš, Jiří; Giri, Chandan; Rissanen, Kari; Lantto, Perttu; Telkki, Ville-Veikko; Schröder, Leif (Nature Publishing Group, 2022)Guest capture and release are important properties of self-assembling nanostructures. Over time, a significant fraction of guests might engage in short-lived states with different symmetry and stereoselectivity and transit ...
Influencing the self‐sorting behavior of [2.2]paracyclophane based ligands by introducing isostructural binding motifs Volbach, Lucia; Struch, Niklas; Bohle, Fabian; Topic, Filip; Schnakenburg, Gregor; Schneider, Andreas; Rissanen, Kari; Grimme, Stefan; Lützen, Arne (Wiley-VCH Verlag, 2020)Two isostructural ligands with either nitrile ( L nit ) or isonitrile ( L iso ) moieties directly connected to a [2.2]paracyclophane backbone with pseudo‐meta substitution pattern have been synthesized. The ligand itself ...
Self-assembly of metallosupramolecular rhombi from chiral concave 9,9'-spirobifluorene-derived bis(pyridine) ligands Hovorka, Rainer; Hytteballe, Sophie; Piehler, Torsten; Meyer-Eppler, Georg; Topic, Filip; Rissanen, Kari; Engeser, Marianne; Lützen, Arne (Beilstein - Institut zur Foerderung der Chemischen Wissenschaften, 2014)Two new 9,9’-spirobifluorene-based bis(4-pyridines) were synthesised in enantiopure and one also in racemic form. These ligands act as concave templates and form metallosupramolecular [(dppp)₂M₂L₂] rhombi with cis-protected ...
Nickel as a Lewis Base in a T‐Shaped Nickel(0) Germylene Complex Incorporating a Flexible Bis(NHC) Ligand Gendy, Chris; Mansikkamäki, Akseli; Valjus, Juuso; Heidebrecht, Joshua; Hui, Paul Chuk-Yan; Bernard, Guy M.; Tuononen, Heikki; Wasylishen, Roderick E.; Michaelis, Vladimir K.; Roesler, Roland (Wiley‐VCH Verlag, 2019)Flexible, chelating bis(NHC) ligand 2, able to accommodate both cis- and trans-coordination modes, was used to synthesize (2)Ni(η 2 -cod), 3. In reaction with GeCl2, this produced (2)NiGeCl2, 4, featuring a T-shaped Ni(0) ...
Subcomponent self‐assembly of a cyclic tetranuclear Fe(II) helicate in a highly diastereoselective self‐sorting manner Anhäuser, Jana; Puttreddy, Rakesh; Glanz, Lukas; Schneider, Andreas; Engeser, Marianne; Rissanen, Kari; Lützen, Arne (Wiley-VCH Verlag, 2019)An enantiomerically pure diamine based on the 4,15‐difunctionalized [2.2]paracyclophane scaffold and 2‐formylpyridine self‐assemble into an optically pure cyclic metallosupramolecular Fe₄L₆ helicate upon mixing with iron(II) ...