Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages
Khariushin, I., Ovsyannikov, A., Baudron, S., Ward, J., Kiesilä, A., Rissanen, K., Kalenius, E., Kovalenko, K., Fedin, V., Solovieva, S., Antipin, I., Bulach, V., & Ferlay, S. (2022). Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages. Chemical Communications, 58(98), 13628-13631. https://doi.org/10.1039/d2cc04510a
Julkaistu sarjassa
Chemical CommunicationsPäivämäärä
2022Oppiaine
Analyyttinen kemiaNanoscience CenterOrgaaninen kemiaAnalytical ChemistryNanoscience CenterOrganic ChemistryTekijänoikeudet
© The Royal Society of Chemistry 2022
Giant octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix[4]arene-supported tetranuclear M(II) clusters (M = Co, Ni) with hybrid linker based on tris(dipyrrinato)cobalt(III) complexes appended with peripherical carboxylic groups. Due to intrinsic and extrinsic porosity, the obtained solid-state supramolecular architectures demonstrated good performance as adsorbents for the separation of industrially important gases mixtures.
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Royal Society of Chemistry (RSC)ISSN Hae Julkaisufoorumista
1359-7345Asiasanat
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This work was supported by the University of Strasbourg, the Institute Universitaire de France, Doctoral Mechnikov scholarship from French Embassy (I. V. K.), the CNRS, the Russian Science Foundation (Project N° 19-73-20035 to I. V. K., A. S. O., S. E. S., I. S. A.), the Government assignment for Nikolaev Institute of RAS (K. A. K., V. P. F.). The authors are grateful to Kurchatov Complex For Syn ...
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