Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages
Khariushin, I., Ovsyannikov, A., Baudron, S., Ward, J., Kiesilä, A., Rissanen, K., Kalenius, E., Kovalenko, K., Fedin, V., Solovieva, S., Antipin, I., Bulach, V., & Ferlay, S. (2022). Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages. Chemical Communications, 58(98), 13628-13631. https://doi.org/10.1039/d2cc04510a
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Chemical CommunicationsDate
2022Discipline
Analyyttinen kemiaNanoscience CenterOrgaaninen kemiaAnalytical ChemistryNanoscience CenterOrganic ChemistryCopyright
© The Royal Society of Chemistry 2022
Giant octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix[4]arene-supported tetranuclear M(II) clusters (M = Co, Ni) with hybrid linker based on tris(dipyrrinato)cobalt(III) complexes appended with peripherical carboxylic groups. Due to intrinsic and extrinsic porosity, the obtained solid-state supramolecular architectures demonstrated good performance as adsorbents for the separation of industrially important gases mixtures.
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Royal Society of Chemistry (RSC)ISSN Search the Publication Forum
1359-7345Keywords
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Academy Project, AoFAdditional information about funding
This work was supported by the University of Strasbourg, the Institute Universitaire de France, Doctoral Mechnikov scholarship from French Embassy (I. V. K.), the CNRS, the Russian Science Foundation (Project N° 19-73-20035 to I. V. K., A. S. O., S. E. S., I. S. A.), the Government assignment for Nikolaev Institute of RAS (K. A. K., V. P. F.). The authors are grateful to Kurchatov Complex For Syn ...
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