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dc.contributor.authorWard, Jas S.
dc.contributor.authorFrontera, Antonio
dc.contributor.authorRissanen, Kari
dc.date.accessioned2021-03-29T06:36:43Z
dc.date.available2021-03-29T06:36:43Z
dc.date.issued2021
dc.identifier.citationWard, J. S., Frontera, A., & Rissanen, K. (2021). Utility of Three-Coordinate Silver Complexes Toward the Formation of Iodonium Ions. <i>Inorganic Chemistry</i>, <i>60</i>(7), 5383-5390. <a href="https://doi.org/10.1021/acs.inorgchem.1c00409" target="_blank">https://doi.org/10.1021/acs.inorgchem.1c00409</a>
dc.identifier.otherCONVID_52588314
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/74864
dc.description.abstractThe work herein describes the synthesis of five three-coordinate silver(I) complexes comprising a bidentate ligand L1, either bpy (2,2′-bipyridyl) or bpyMe2 (4,4′-dimethyl-2,2′-dipyridyl), and a monodentate ligand L2, either mtz (1-methyl-1H-1,2,3-triazole), 4-Etpy (4-ethylpyridine), or 4-DMAP (N,N-dimethylpyridin-4-amine). Upon reaction of the three-coordinate silver(I) complexes with 0.5 equiv of I2, the reactions quantitatively produce a 1:1 pair of complexes of a four-coordinate silver(I) complex [Ag(L1)2]PF6 and a two-coordinate iodonium complex [I(L2)2]PF6. The combination of [Ag(bpyMe2)2]PF6 and [I(4-DMAP)2]PF6 gave rise to an I+···Ag+ interaction where the I+ acts as a nucleophile, only the second example of which, that was observed in both the solution (NMR) and solid (X-ray) states.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherAmerican Chemical Society (ACS)
dc.relation.ispartofseriesInorganic Chemistry
dc.rightsCC BY 4.0
dc.titleUtility of Three-Coordinate Silver Complexes Toward the Formation of Iodonium Ions
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202103292197
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange5383-5390
dc.relation.issn0020-1669
dc.relation.numberinseries7
dc.relation.volume60
dc.type.versionpublishedVersion
dc.rights.copyright© 2021 the Authors
dc.rights.accesslevelopenAccessfi
dc.subject.ysokemialliset yhdisteet
dc.subject.ysoligandit
dc.subject.ysokemiallinen synteesi
dc.subject.ysohopea
dc.subject.ysokompleksiyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p324
jyx.subject.urihttp://www.yso.fi/onto/yso/p24741
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p7409
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1021/acs.inorgchem.1c00409
jyx.fundinginformationJ.S.W. gratefully acknowledges the Finnish Cultural Foundation Central Fund (Grant Number 00201148) for funding. A.F. thanks the MICIU/AEI from Spain for financial support (Project CTQ2017-85821-R, Feder funds).


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