1,2‐Benzothiazine Derivatives from Sulfonimidamides by Metal‐Catalyzed Annulation Reactions in Solution and under Solvent‐Free Mechanochemical Conditions
| dc.contributor.author | Schöbel, Jan-Hendrik | |
| dc.contributor.author | Elbers, Philipp | |
| dc.contributor.author | Truong, Khai-Nghi | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Bolm, Carsten | |
| dc.date.accessioned | 2021-02-08T14:15:48Z | |
| dc.date.available | 2021-02-08T14:15:48Z | |
| dc.date.issued | 2021 | |
| dc.identifier.citation | Schöbel, J.-H., Elbers, P., Truong, K.-N., Rissanen, K., & Bolm, C. (2021). 1,2‐Benzothiazine Derivatives from Sulfonimidamides by Metal‐Catalyzed Annulation Reactions in Solution and under Solvent‐Free Mechanochemical Conditions. <i>Advanced Synthesis and Catalysis</i>, <i>363</i>(5), 1322-1329. <a href="https://doi.org/10.1002/adsc.202001505" target="_blank">https://doi.org/10.1002/adsc.202001505</a> | |
| dc.identifier.other | CONVID_47788325 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/74041 | |
| dc.description.abstract | Three‐dimensional aza‐analogues of 1,2‐benzothiazine 1,1‐dioxides have been prepared from sulfonimidamides. Two different protocols are presented. The first is a rhodium‐catalyzed annulation reaction with alpha‐sulfonyloxyketones leading to 4 unsubstituted benzothiazine derivatives. By selective bromination with NBS the heterocyclic ring can further be functionalized. In the second approach, an iridium catalyst is applied under solvent‐free mechanochemical conditions providing products with 3,4‐disubstituted thiazine rings from diazoketo esters and diazoketo sulfones. | en |
| dc.format.mimetype | application/pdf | |
| dc.language | eng | |
| dc.language.iso | eng | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.relation.ispartofseries | Advanced Synthesis and Catalysis | |
| dc.rights | CC BY 4.0 | |
| dc.subject.other | 1,2-benzothiazine | |
| dc.subject.other | C−H activation | |
| dc.subject.other | mechanochemistry | |
| dc.subject.other | iridium catalysis | |
| dc.subject.other | rhodium catalysis | |
| dc.subject.other | sulfonimidamide | |
| dc.title | 1,2‐Benzothiazine Derivatives from Sulfonimidamides by Metal‐Catalyzed Annulation Reactions in Solution and under Solvent‐Free Mechanochemical Conditions | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202102081483 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Orgaaninen kemia | fi |
| dc.contributor.oppiaine | Organic Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 1322-1329 | |
| dc.relation.issn | 1615-4150 | |
| dc.relation.numberinseries | 5 | |
| dc.relation.volume | 363 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2021 the Authors | |
| dc.rights.accesslevel | openAccess | fi |
| dc.subject.yso | katalyysi | |
| dc.subject.yso | orgaaniset yhdisteet | |
| dc.subject.yso | kemiallinen synteesi | |
| dc.subject.yso | rikkiyhdisteet | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8704 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p3841 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8468 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p5731 | |
| dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
| dc.relation.doi | 10.1002/adsc.202001505 | |
| dc.type.okm | A1 |
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