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dc.contributor.authorSchöbel, Jan-Hendrik
dc.contributor.authorElbers, Philipp
dc.contributor.authorTruong, Khai-Nghi
dc.contributor.authorRissanen, Kari
dc.contributor.authorBolm, Carsten
dc.date.accessioned2021-02-08T14:15:48Z
dc.date.available2021-02-08T14:15:48Z
dc.date.issued2021
dc.identifier.citationSchöbel, J.-H., Elbers, P., Truong, K.-N., Rissanen, K., & Bolm, C. (2021). 1,2‐Benzothiazine Derivatives from Sulfonimidamides by Metal‐Catalyzed Annulation Reactions in Solution and under Solvent‐Free Mechanochemical Conditions. <i>Advanced Synthesis and Catalysis</i>, <i>363</i>(5), 1322-1329. <a href="https://doi.org/10.1002/adsc.202001505" target="_blank">https://doi.org/10.1002/adsc.202001505</a>
dc.identifier.otherCONVID_47788325
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/74041
dc.description.abstractThree‐dimensional aza‐analogues of 1,2‐benzothiazine 1,1‐dioxides have been prepared from sulfonimidamides. Two different protocols are presented. The first is a rhodium‐catalyzed annulation reaction with alpha‐sulfonyloxyketones leading to 4 unsubstituted benzothiazine derivatives. By selective bromination with NBS the heterocyclic ring can further be functionalized. In the second approach, an iridium catalyst is applied under solvent‐free mechanochemical conditions providing products with 3,4‐disubstituted thiazine rings from diazoketo esters and diazoketo sulfones.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAdvanced Synthesis and Catalysis
dc.rightsCC BY 4.0
dc.subject.other1,2-benzothiazine
dc.subject.otherC−H activation
dc.subject.othermechanochemistry
dc.subject.otheriridium catalysis
dc.subject.otherrhodium catalysis
dc.subject.othersulfonimidamide
dc.title1,2‐Benzothiazine Derivatives from Sulfonimidamides by Metal‐Catalyzed Annulation Reactions in Solution and under Solvent‐Free Mechanochemical Conditions
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202102081483
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange1322-1329
dc.relation.issn1615-4150
dc.relation.numberinseries5
dc.relation.volume363
dc.type.versionpublishedVersion
dc.rights.copyright© 2021 the Authors
dc.rights.accesslevelopenAccessfi
dc.subject.ysokatalyysi
dc.subject.ysoorgaaniset yhdisteet
dc.subject.ysokemiallinen synteesi
dc.subject.ysorikkiyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p8704
jyx.subject.urihttp://www.yso.fi/onto/yso/p3841
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p5731
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1002/adsc.202001505


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