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dc.contributor.authorKatlenok, Eugenе A.
dc.contributor.authorHaukka, Matti
dc.contributor.authorLevin, Oleg V.
dc.contributor.authorFrontera, Antonio
dc.contributor.authorKukushkin, Vadim Yurievich
dc.date.accessioned2020-04-07T08:19:31Z
dc.date.available2020-04-07T08:19:31Z
dc.date.issued2020
dc.identifier.citationKatlenok, E. A., Haukka, M., Levin, O. V., Frontera, A., & Kukushkin, V. Y. (2020). Supramolecular Assembly of Metal Complexes by (Aryl)I⋯dz2[PtII] Halogen Bond. <i>Chemistry : A European Journal</i>, <i>26</i>(34), 7692-7701. <a href="https://doi.org/10.1002/chem.202001196" target="_blank">https://doi.org/10.1002/chem.202001196</a>
dc.identifier.otherCONVID_35177363
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/68482
dc.description.abstractThe theoretical data for the half‐lantern complexes [Pt(C^N)(μ‐S^N)] 2 ( 1 – 3 ; С^N is cyclometalated 2‐Ph‐benzothiazole; S^N is 2‐SH‐pyridine 1 , 2‐SH‐benzoxazole 2 , 2‐SH‐tetrafluorobenzothiazole 3 ) indicate that the Pt···Pt orbital interaction leads to an increment of the nucleophilicity of the outer d z 2 ‐orbitals to provide assembly with electrophilic species. 1 – 3 were co‐crystallized with bifunctional halogen bond (XB) donors to give adducts ( 1 – 3 ) 2 ∙(1,4‐diiodotetrafluorobenzene) and infinite polymeric [ 1 ·1,1’‐diiodoperfluorodiphenyl] n . X‐ray crystallography revealed that the supramolecular assembly is achieved via (Aryl)I∙∙∙ d z 2 [Pt II ] XB between iodine σ‐holes and lone pairs of the positively charged (Pt II ) 2 centers, acting as nucleophilic sites. The polymer includes a curved linear chain ···Pt 2 ···I(arene F )I···Pt 2 ··· involving XB between iodines of the perfluoroarene linkers and (Pt II ) 2 moieties. The 195 Pt NMR, UV‐vis, and CV studies indicate that XB is preserved in CH(D) 2 Cl 2 solutions.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesChemistry : A European Journal
dc.rightsIn Copyright
dc.subject.otherhalogen bonding
dc.subject.othersupramolecular chemistry
dc.subject.othercyclometalated complex
dc.subject.otherplatinum
dc.subject.othertheoretical calculations
dc.titleSupramolecular Assembly of Metal Complexes by (Aryl)I⋯dz2[PtII] Halogen Bond
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202004072697
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange7692-7701
dc.relation.issn0947-6539
dc.relation.numberinseries34
dc.relation.volume26
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
dc.rights.accesslevelopenAccessfi
dc.subject.ysosupramolekulaarinen kemia
dc.subject.ysoplatina
dc.subject.ysokemialliset sidokset
dc.subject.ysokompleksiyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
jyx.subject.urihttp://www.yso.fi/onto/yso/p12535
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/chem.202001196
jyx.fundinginformationSupport of the synthetic work and compound characterizations from the Russian Foundation for Basic Research (grant 18-29-04006) is gratefully acknowledged. Electrochemical part of this work was supported by the Russian Foundation for Basic Research project 19-29-08026. E.A.K. is thankful to the Saint Petersburg State University for postdoctoral fellowship. Physicochemical studies were performed at the Center for Magnetic Resonance, Center for Xray Diffraction Studies, and Center for Chemical Analysis and Materials Research (all belonging to Saint Petersburg State University). V.Y.K. is grateful to South Ural State University (Act 211 Government of the Russian Federation, contract No 02.A03.21.0011) for putting facilities at his disposal. We are indebted to Prof. Dr. P.M. Tolstoy and Dr. D.M. Ivanov for valuable suggestions and Dr. A.V. Rozhkov for kind loan of 1,1’-FIDB and 2-mercapto4,5,6,7-tetrafluorobenzothiazole.
dc.type.okmA1


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