University of Jyväskylä | JYX Digital Repository

  • English  | Give feedback |
    • suomi
    • English
 
  • Login
JavaScript is disabled for your browser. Some features of this site may not work without it.
View Item 
  • JYX
  • Opinnäytteet
  • Pro gradu -tutkielmat
  • View Item
JYX > Opinnäytteet > Pro gradu -tutkielmat > View Item

Anion recognition by halogen bonding

Thumbnail
View/Open
5.3 Mb

Downloads:  
Show download detailsHide download details  
Authors
Lehikoinen, Arttu
Date
2022
Discipline
KemiaChemistry
Copyright
This publication is copyrighted. You may download, display and print it for Your own personal use. Commercial use is prohibited.

 
Kirjallisuuskatsauksessa esitellään anionien tunnistus käsitteenä ja siihen liittyviä keskeisiä aiheita, ensisijaisesti halogeenisidos, käydään läpi. Myös halogeenisidosanionireseptorit ja niiden suunnittelun eri näkökulmat esitellään. Lopuksi tähänastinen tutkimus anionien aistimisesta halogeenisidosten avulla käydään lyhyesti läpi. Kokeellisessa osuudessa suoritettiin 17 synteesiä, joiden tavoitteena oli muodostaa neutraaleja reseptorimolekyylejä, jotka kykenisivät sitomaan anioneita halogeenisidoksilla. Synteeseissä käytettiin viittä eri päälähtöainetta: 3-jodianiliinia, 3bromianiliinia, 2-amino-6-bromipyridiiniä, sekä 1,3-dietynyylibentseeniä ja isoftaloyylidikloridia. Tavoitereseptoreita ei saatu syntetisoitua, mutta yksi uudenlainen sivutuote löydettiin synteeseistä.
 
In the literature review, anion recognition and key concepts of it, predominantly halogen bonding, are introduced. The different aspects of halogen bonding anion receptors, and the objectives for their design are discussed. Lastly, a brief overview of halogen bond mediated anion sensing is given. In the experimental section, 17 syntheses were performed to create neutral receptor molecules that could bind anions using halogen bonds. Five different primary reagents were used, 3-iodoaniline, 3-bromoaniline, 2-amino-6-bromopyridine, as well as 1,3-diethynylbenzene and isophthaloyl dichloride. No receptors were successfully synthesized but a novel by-product was obtained.
 
Keywords
halogen bond halogen bonding XB supramolecular chemistry anion recognition anion sensor anion sensing non-covalent anion receptor receptor 'click' reaction click reaction CuAAC receptor design sensor design sigma-hole sigma hole XB-donor XB donor XB-acceptor XB acceptor oxyanion halide pseudohalogen spacer group binding unit MIM halogeenit kemialliset sidokset orgaaninen kemia anionit anturit halogens chemical bonds organic chemistry anions sensors
URI

http://urn.fi/URN:NBN:fi:jyu-202207253956

Metadata
Show full item record
Collections
  • Pro gradu -tutkielmat [25543]

Related items

Showing items with similar title or keywords.

  • Design and construction of halogen-bonded capsules and cages 

    Turunen, Lotta (University of Jyväskylä, 2017)
    This thesis describes the design, synthesis and characterization of supramolecular halogen-bonded capsules and cages from multivalent ligands. In the first part of the thesis, an overview to halogen bonding is provided. ...
  • Ion pair recognition by ditopic crown ether based bis-urea and uranyl salophen receptors 

    Mäkelä, Toni (University of Jyväskylä, 2016)
  • Short X···N Halogen Bonds With Hexamethylenetetraamine as the Acceptor 

    Anyfanti, Goulielmina; Bauzá, Antonio; Gentiluomo, Lorenzo; Rodrigues, João; Portalone, Gustavo; Frontera, Antonio; Rissanen, Kari; Puttreddy, Rakesh (Frontiers Media SA, 2021)
    Hexamethylenetetramine (HMTA) and N-haloimides form two types of short (imide)X···N and X–X···N (X = Br, I) halogen bonds. Nucleophilic substitution or ligand-exchange reaction on the peripheral X of X–X···N with the ...
  • Definition of the chalcogen bond (IUPAC Recommendations 2019) 

    Aakeroy, Christer B.; Bryce, David L.; Desiraju, Gautam R.; Frontera, Antonio; Legon, Anthony C.; Nicotra, Francesco; Rissanen, Kari; Scheiner, Steve; Terraneo, Giancarlo; Metrangolo, Pierangelo; Resnati, Giuseppe (De Gruyter, 2019)
    This recommendation proposes a definition for the term “chalcogen bond”; it is recommended the term is used to designate the specific subset of inter- and intramolecular interactions formed by chalcogen atoms wherein the ...
  • Anion Responsive Molecular Switch Based on a Doubly‐Strapped Calix[4]pyrrole 

    Helttunen, Kaisa (Wiley-VCH Verlag, 2022)
    A calix[4]pyrrole receptor bearing two proximally meso - meso linking isophthaloyl straps displays open and closed states depending on the calix[4]pyrrole conformation. In the crystal structures and in non-polar solvent, ...
  • Browse materials
  • Browse materials
  • Articles
  • Conferences and seminars
  • Electronic books
  • Historical maps
  • Journals
  • Tunes and musical notes
  • Photographs
  • Presentations and posters
  • Publication series
  • Research reports
  • Research data
  • Study materials
  • Theses

Browse

All of JYXCollection listBy Issue DateAuthorsSubjectsPublished inDepartmentDiscipline

My Account

Login

Statistics

View Usage Statistics
  • How to publish in JYX?
  • Self-archiving
  • Publish Your Thesis Online
  • Publishing Your Dissertation
  • Publication services

Open Science at the JYU
 
Data Protection Description

Accessibility Statement

Unless otherwise specified, publicly available JYX metadata (excluding abstracts) may be freely reused under the CC0 waiver.
Open Science Centre