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Chiral self-sorting behaviour of [2.2]paracyclophane-based bis(pyridine) ligands

dc.contributor.authorAnhäuser, J.
dc.contributor.authorPuttreddy, Rakesh
dc.contributor.authorLorenz, Y.
dc.contributor.authorSchneider, A.
dc.contributor.authorEngeser, M.
dc.contributor.authorRissanen, Kari
dc.contributor.authorLützen, A.
dc.date.accessioned2020-01-27T12:18:28Z
dc.date.available2020-03-15T22:35:14Z
dc.date.issued2019
dc.identifier.citationAnhäuser, J., Puttreddy, R., Lorenz, Y., Schneider, A., Engeser, M., Rissanen, K., & Lützen, A. (2019). Chiral self-sorting behaviour of [2.2]paracyclophane-based bis(pyridine) ligands. <i>Organic Chemistry Frontiers</i>, <i>6</i>(8), 1226-1235. <a href="https://doi.org/10.1039/c9qo00155g" target="_blank">https://doi.org/10.1039/c9qo00155g</a>
dc.identifier.otherCONVID_28993412
dc.identifier.otherTUTKAID_81085
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/67543
dc.description.abstractTwo constitutionally isomeric chiral bis(pyridine) ligands based on planar chiral 4,15-difunctionalized [2.2]paracyclophanes were synthesized, the respective enantiomers were separated via HPLC on a chiral stationary phase, and their self-assembly behaviour upon coordination to palladium(ii) ions was studied with regard to chiral self-sorting effects. As proven by NMR spectroscopy, mass spectrometry, CD spectroscopy, UV-Vis spectroscopy and X-ray crystallography both ligands form the expected dinuclear complexes upon coordination to cis-protected di- or tetravalent palladium(ii) ions, respectively, however, with distinct differences concerning their chiral self-sorting ability.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesOrganic Chemistry Frontiers
dc.rightsIn Copyright
dc.subject.otherX ray crystallography
dc.subject.otherCircular dichroism spectroscopy
dc.subject.otherLigands
dc.subject.otherMass spectrometry
dc.subject.otherNuclear magnetic resonance spectroscopy
dc.subject.otherPalladium compounds
dc.subject.otherPyridine
dc.subject.otherSynthesis (chemical)
dc.subject.otherUltraviolet visible spectroscopy
dc.titleChiral self-sorting behaviour of [2.2]paracyclophane-based bis(pyridine) ligands
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202001231714
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2020-01-23T07:15:22Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange1226-1235
dc.relation.issn2052-4110
dc.relation.numberinseries8
dc.relation.volume6
dc.type.versionacceptedVersion
dc.rights.copyright© the Partner Organisations 2019
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber298817
dc.subject.ysomassaspektrometria
dc.subject.ysokidetiede
dc.subject.ysoorgaaninen kemia
dc.subject.ysoNMR-spektroskopia
dc.subject.ysoligandit
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p10755
jyx.subject.urihttp://www.yso.fi/onto/yso/p643
jyx.subject.urihttp://www.yso.fi/onto/yso/p11902
jyx.subject.urihttp://www.yso.fi/onto/yso/p26254
jyx.subject.urihttp://www.yso.fi/onto/yso/p24741
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1039/c9qo00155g
dc.relation.funderSuomen Akatemiafi
dc.relation.funderResearch Council of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
jyx.fundinginformationAuthors acknowledge the Studienstiftung des deutschen Volkes for a doctoral scholarship and the Bonn International Graduate School of Chemistry for an international research scholarship (J. A.), the Academy of Finland (RP: 298817) and the University of Jyväskylä (KR), Finland for financial support. We thank Christine Sondag and Karin Peters-Pflaumbaum for their support in measuring the EI-and ESI-MS spectra.
dc.type.okmA1


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