Synthesis of silacyclopent-2-en-4-ols via intramolecular [2 + 2] photocycloaddition of benzoyl(allyl)silanes
Vale, J. R., Valkonen, A., Afonso, C. A. M., & Candeias, N. R. (2019). Synthesis of silacyclopent-2-en-4-ols via intramolecular [2 + 2] photocycloaddition of benzoyl(allyl)silanes. Organic Chemistry Frontiers, 6(22), 3793-3798. https://doi.org/10.1039/C9QO01028A
Julkaistu sarjassa
Organic Chemistry FrontiersPäivämäärä
2019Tekijänoikeudet
© Authors, 2019
Organosilicon compounds are versatile units with a wide range of uses from medicinal chemistry to the field of organic electronics. An unprecedented method for the synthesis of novel diaryl-substituted silacyclopentenols via blue-light promoted intramolecular [2 + 2] photocycloaddition of acyl silanes is herein disclosed. Additionally, the present findings demonstrate the influence of the olefin substituents in controlling the regioselectivity of the intramolecular Paternò–Büchi reaction, providing silacycles different from previously reported ones. The high degree of functionalization of these compounds makes them attractive precursors to other synthetically challenging silacyclopentanes.
Julkaisija
Royal Society of ChemistryISSN Hae Julkaisufoorumista
2052-4110Asiasanat
Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/33616371
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Näytä kaikki kuvailutiedotKokoelmat
Rahoittaja(t)
Suomen AkatemiaRahoitusohjelmat(t)
Akatemiatutkijan tutkimuskulut, SALisätietoja rahoituksesta
The Academy of Finland is duly acknowledged for financial support to N. R. C. (Decisions No. 326487 and 326486) and to A. V. (No. 314343). Fundação para a Ciência e Tecnologia (FCT) is acknowledged for financial support to JRV (SFRH/BD/ 120119/2016). CSC-IT Center for Science Ltd, Finland is acknowledged for the allocation of computational resources.Lisenssi
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