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dc.contributor.authorVale, Joao R.
dc.contributor.authorValkonen, Arto
dc.contributor.authorAfonso, Carlos A. M.
dc.contributor.authorCandeias, Nuno R.
dc.date.accessioned2019-11-26T11:33:08Z
dc.date.available2019-11-26T11:33:08Z
dc.date.issued2019
dc.identifier.citationVale, J. R., Valkonen, A., Afonso, C. A. M., & Candeias, N. R. (2019). Synthesis of silacyclopent-2-en-4-ols via intramolecular [2 + 2] photocycloaddition of benzoyl(allyl)silanes. <i>Organic Chemistry Frontiers</i>, <i>6</i>(22), 3793-3798. <a href="https://doi.org/10.1039/C9QO01028A" target="_blank">https://doi.org/10.1039/C9QO01028A</a>
dc.identifier.otherCONVID_33616371
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/66524
dc.description.abstractOrganosilicon compounds are versatile units with a wide range of uses from medicinal chemistry to the field of organic electronics. An unprecedented method for the synthesis of novel diaryl-substituted silacyclopentenols via blue-light promoted intramolecular [2 + 2] photocycloaddition of acyl silanes is herein disclosed. Additionally, the present findings demonstrate the influence of the olefin substituents in controlling the regioselectivity of the intramolecular Paternò–Büchi reaction, providing silacycles different from previously reported ones. The high degree of functionalization of these compounds makes them attractive precursors to other synthetically challenging silacyclopentanes.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesOrganic Chemistry Frontiers
dc.rightsCC BY-NC 3.0
dc.titleSynthesis of silacyclopent-2-en-4-ols via intramolecular [2 + 2] photocycloaddition of benzoyl(allyl)silanes
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201911265014
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange3793-3798
dc.relation.issn2052-4110
dc.relation.numberinseries22
dc.relation.volume6
dc.type.versionpublishedVersion
dc.rights.copyright© Authors, 2019
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber314343
dc.subject.ysopii
dc.subject.ysokemiallinen synteesi
dc.subject.ysoorganometalliyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p15609
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
dc.rights.urlhttps://creativecommons.org/licenses/by-nc/3.0/
dc.relation.doi10.1039/C9QO01028A
dc.relation.funderSuomen Akatemiafi
dc.relation.funderResearch Council of Finlanden
jyx.fundingprogramAkatemiatutkijan tutkimuskulut, SAfi
jyx.fundingprogramResearch costs of Academy Research Fellow, AoFen
jyx.fundinginformationThe Academy of Finland is duly acknowledged for financial support to N. R. C. (Decisions No. 326487 and 326486) and to A. V. (No. 314343). Fundação para a Ciência e Tecnologia (FCT) is acknowledged for financial support to JRV (SFRH/BD/ 120119/2016). CSC-IT Center for Science Ltd, Finland is acknowledged for the allocation of computational resources.
dc.type.okmA1


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