dc.contributor.author | Vale, Joao R. | |
dc.contributor.author | Valkonen, Arto | |
dc.contributor.author | Afonso, Carlos A. M. | |
dc.contributor.author | Candeias, Nuno R. | |
dc.date.accessioned | 2019-11-26T11:33:08Z | |
dc.date.available | 2019-11-26T11:33:08Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Vale, J. R., Valkonen, A., Afonso, C. A. M., & Candeias, N. R. (2019). Synthesis of silacyclopent-2-en-4-ols via intramolecular [2 + 2] photocycloaddition of benzoyl(allyl)silanes. <i>Organic Chemistry Frontiers</i>, <i>6</i>(22), 3793-3798. <a href="https://doi.org/10.1039/C9QO01028A" target="_blank">https://doi.org/10.1039/C9QO01028A</a> | |
dc.identifier.other | CONVID_33616371 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/66524 | |
dc.description.abstract | Organosilicon compounds are versatile units with a wide range of uses from medicinal chemistry to the field of organic electronics. An unprecedented method for the synthesis of novel diaryl-substituted silacyclopentenols via blue-light promoted intramolecular [2 + 2] photocycloaddition of acyl silanes is herein disclosed. Additionally, the present findings demonstrate the influence of the olefin substituents in controlling the regioselectivity of the intramolecular Paternò–Büchi reaction, providing silacycles different from previously reported ones. The high degree of functionalization of these compounds makes them attractive precursors to other synthetically challenging silacyclopentanes. | en |
dc.format.mimetype | application/pdf | |
dc.language | eng | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.relation.ispartofseries | Organic Chemistry Frontiers | |
dc.rights | CC BY-NC 3.0 | |
dc.title | Synthesis of silacyclopent-2-en-4-ols via intramolecular [2 + 2] photocycloaddition of benzoyl(allyl)silanes | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201911265014 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Orgaaninen kemia | fi |
dc.contributor.oppiaine | Organic Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 3793-3798 | |
dc.relation.issn | 2052-4110 | |
dc.relation.numberinseries | 22 | |
dc.relation.volume | 6 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © Authors, 2019 | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 314343 | |
dc.subject.yso | pii | |
dc.subject.yso | kemiallinen synteesi | |
dc.subject.yso | organometalliyhdisteet | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p15609 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p8468 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p28123 | |
dc.rights.url | https://creativecommons.org/licenses/by-nc/3.0/ | |
dc.relation.doi | 10.1039/C9QO01028A | |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Research Council of Finland | en |
jyx.fundingprogram | Akatemiatutkijan tutkimuskulut, SA | fi |
jyx.fundingprogram | Research costs of Academy Research Fellow, AoF | en |
jyx.fundinginformation | The Academy of Finland is duly acknowledged for financial support to N. R. C. (Decisions No. 326487 and 326486) and to A. V. (No. 314343). Fundação para a Ciência e Tecnologia (FCT) is acknowledged for financial support to JRV (SFRH/BD/ 120119/2016). CSC-IT Center for Science Ltd, Finland is acknowledged for the allocation of computational resources. | |
dc.type.okm | A1 | |