Oxidovanadium(v) complexes with l-proline-based amino acid phenolates
Abstract
L-proline was used to prepare chiral, tridentate amino acid phenol proligands H2L1—4. These
proligands react with vanadium precursors VO(acac)2, VOSO4 ∙ 5 H2O and VO(OPr)3 in
methanol to form the corresponding oxidoalkoxidovanadium(V) complexes 1—4. The
complexes crystallize from methanol, and are octahedrally coordinated with a general
formula [VO(L1—4)(OMe)(MeOH)]. In solution, however, they adopt several different
conformations or isomeric structures depending on the solvent.
Main Authors
Format
Articles
Research article
Published
2019
Series
Subjects
Publication in research information system
Publisher
Elsevier BV
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201905242777Use this for linking
Review status
Peer reviewed
ISSN
0020-1693
DOI
https://doi.org/10.1016/j.ica.2019.02.011
Language
English
Published in
Inorganica Chimica Acta
Citation
- Salonen, P., Peuronen, A., Sinkkonen, J., & Lehtonen, A. (2019). Oxidovanadium(v) complexes with l-proline-based amino acid phenolates. Inorganica Chimica Acta, 489, 108-114. https://doi.org/10.1016/j.ica.2019.02.011
License
Copyright© 2019 Elsevier B.V.