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dc.contributor.authorLahtinen, Elmeri
dc.contributor.authorPrecker, Rafaella
dc.contributor.authorLahtinen, Manu
dc.contributor.authorHey-Hawkins, Evamarie
dc.contributor.authorHaukka, Matti
dc.date.accessioned2019-03-07T09:05:19Z
dc.date.available2020-02-09T22:35:23Z
dc.date.issued2019
dc.identifier.citationLahtinen, E., Precker, R., Lahtinen, M., Hey-Hawkins, E., & Haukka, M. (2019). Selective Laser Sintering of Metal-Organic Frameworks : Production of Highly Porous Filters by 3D Printing onto a Polymeric Matrix. <i>ChemPlusChem</i>, <i>84</i>(2), 222-225. <a href="https://doi.org/10.1002/cplu.201900081" target="_blank">https://doi.org/10.1002/cplu.201900081</a>
dc.identifier.otherCONVID_28909918
dc.identifier.otherTUTKAID_80592
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/63058
dc.description.abstractMetal‐organic frameworks (MOFs) have raised a lot of interest, especially as adsorbing materials, because of their unique and well‐defined pore structures. One of the main challenges in the utilization of MOFs is their crystalline and powdery nature, which makes their use inconvenient in practice. Three‐dimensional printing has been suggested as a potential solution to overcome this problem. We used selective laser sintering (SLS) to print highly porous flow‐through filters containing the MOF copper(II) benzene‐1,3,5‐tricarboxylate (HKUST‐1). These filters were printed simply by mixing HKUST‐1 with an easily printable nylon‐12 polymer matrix. By using the SLS, powdery particles were fused together in such a way that the structure of the printed solid material resembles the structure of a powder bed. The MOF additive is firmly attached only on the surface of partially fused polymer particles and therefore remains accessible to fluids passing through the filter. Powder X‐ray analysis of the printed object confirmed that printing did not have any negative impact on the structure of the MOF. CO2‐adsorption studies also showed that the activity of the MOF was not affected by the printing process. SLS offers a straightforward and easy way to fabricate tailor‐made MOF‐containing filters for practical applications.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA
dc.relation.ispartofseriesChemPlusChem
dc.rightsIn Copyright
dc.subject.otherlaser sintering
dc.subject.othermetal-organic frameworks
dc.titleSelective Laser Sintering of Metal-Organic Frameworks : Production of Highly Porous Filters by 3D Printing onto a Polymeric Matrix
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201903041715
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2019-03-04T10:15:11Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange222-225
dc.relation.issn2192-6506
dc.relation.numberinseries2
dc.relation.volume84
dc.type.versionacceptedVersion
dc.rights.copyright© 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.rights.accesslevelopenAccessfi
dc.subject.ysoorganometalliyhdisteet
dc.subject.ysopolymeerit
dc.subject.ysomateriaalitiede
dc.subject.ysohuokoisuus
dc.subject.yso3D-tulostus
dc.subject.ysoadsorptio
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
jyx.subject.urihttp://www.yso.fi/onto/yso/p926
jyx.subject.urihttp://www.yso.fi/onto/yso/p14779
jyx.subject.urihttp://www.yso.fi/onto/yso/p13541
jyx.subject.urihttp://www.yso.fi/onto/yso/p27475
jyx.subject.urihttp://www.yso.fi/onto/yso/p13395
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/cplu.201900081
dc.type.okmA1


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