Coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl radical
Morgan, I., Mansikkamäki, A., Rouzières, M., Clérac, R., & Tuononen, H. (2017). Coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl radical. Dalton Transactions, 46(38), 12790-12793. https://doi.org/10.1039/C7DT02766D
Julkaistu sarjassa
Dalton TransactionsTekijät
Päivämäärä
2017Oppiaine
Epäorgaaninen ja analyyttinen kemiaNanoscience CenterInorganic and Analytical ChemistryNanoscience CenterTekijänoikeudet
© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
The first lanthanide complex of a 1,2,4-benzotriazinyl radical (1), Dy(1)(tbacac)3 (2, tbacac = 2,2,6,6-tetramethyl-3,5-heptane-dionato), was synthesised and found to have an antiferromagnetically ordered ground state with a metamagnetic phase diagram and a critical field of 0.91 T at 1.85 K. The application of a small dc field revealed the single-molecule magnet behaviour of 2, illustrating the coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization.
Julkaisija
Royal Society of ChemistryISSN Hae Julkaisufoorumista
1477-9226Asiasanat
Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/27251858
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Suomen AkatemiaRahoitusohjelmat(t)
Akatemiahanke, SALisätietoja rahoituksesta
This work was supported by the Technology Industries of Finland Centennial Foundation, the Academy of Finland (projects 282499 and 289172), the University of Jyväskylä, the University of Bordeaux, the Région Aquitaine, the ANR, the CNRS, and the GdR MCM-2. We thank Lab. Tech. Elina Hautakangas for elemental analyses and Dr Anssi Peuronen for crystallographic insight.Samankaltainen aineisto
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