dc.contributor.author | Morgan, Ian | |
dc.contributor.author | Mansikkamäki, Akseli | |
dc.contributor.author | Rouzières, Mathieu | |
dc.contributor.author | Clérac, Rodolphe | |
dc.contributor.author | Tuononen, Heikki | |
dc.date.accessioned | 2017-11-13T07:40:22Z | |
dc.date.available | 2018-09-13T21:36:07Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Morgan, I., Mansikkamäki, A., Rouzières, M., Clérac, R., & Tuononen, H. (2017). Coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl radical. <i>Dalton Transactions</i>, <i>46</i>(38), 12790-12793. <a href="https://doi.org/10.1039/C7DT02766D" target="_blank">https://doi.org/10.1039/C7DT02766D</a> | |
dc.identifier.other | CONVID_27251858 | |
dc.identifier.other | TUTKAID_75158 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/55850 | |
dc.description.abstract | The first lanthanide complex of a 1,2,4-benzotriazinyl radical (1), Dy(1)(tbacac)3 (2, tbacac = 2,2,6,6-tetramethyl-3,5-heptane-dionato), was synthesised and found to have an antiferromagnetically ordered ground state with a metamagnetic phase diagram and a critical field of 0.91 T at 1.85 K. The application of a small dc field revealed the single-molecule magnet behaviour of 2, illustrating the coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization. | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.relation.ispartofseries | Dalton Transactions | |
dc.subject.other | kompleksiyhdisteet | |
dc.subject.other | harvinaiset maametallit | |
dc.subject.other | magnetismi | |
dc.subject.other | coordination complexes | |
dc.subject.other | rare earth metals | |
dc.subject.other | magnetism | |
dc.title | Coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl radical | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201711024124 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2017-11-02T13:15:47Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 12790-12793 | |
dc.relation.issn | 1477-9226 | |
dc.relation.numberinseries | 38 | |
dc.relation.volume | 46 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 282499 | |
dc.relation.grantnumber | 289172 | |
dc.subject.yso | kompleksiyhdisteet | |
dc.subject.yso | magnetismi | |
dc.subject.yso | harvinaiset maametallit | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p7808 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p15798 | |
dc.relation.doi | 10.1039/C7DT02766D | |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
jyx.fundingprogram | Akatemiahanke, SA | fi |
jyx.fundingprogram | Akatemiahanke, SA | fi |
jyx.fundingprogram | Academy Project, AoF | en |
jyx.fundingprogram | Academy Project, AoF | en |
jyx.fundinginformation | This work was supported by the Technology Industries of Finland Centennial Foundation, the Academy of Finland (projects 282499 and 289172), the University of Jyväskylä, the University of Bordeaux, the Région Aquitaine, the ANR, the CNRS, and the GdR MCM-2. We thank Lab. Tech. Elina Hautakangas for elemental analyses and Dr Anssi Peuronen for crystallographic insight. | |
dc.type.okm | A1 | |