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dc.contributor.authorMorgan, Ian
dc.contributor.authorMansikkamäki, Akseli
dc.contributor.authorRouzières, Mathieu
dc.contributor.authorClérac, Rodolphe
dc.contributor.authorTuononen, Heikki
dc.date.accessioned2017-11-13T07:40:22Z
dc.date.available2018-09-13T21:36:07Z
dc.date.issued2017
dc.identifier.citationMorgan, I., Mansikkamäki, A., Rouzières, M., Clérac, R., & Tuononen, H. (2017). Coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl radical. <i>Dalton Transactions</i>, <i>46</i>(38), 12790-12793. <a href="https://doi.org/10.1039/C7DT02766D" target="_blank">https://doi.org/10.1039/C7DT02766D</a>
dc.identifier.otherCONVID_27251858
dc.identifier.otherTUTKAID_75158
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/55850
dc.description.abstractThe first lanthanide complex of a 1,2,4-benzotriazinyl radical (1), Dy(1)(tbacac)3 (2, tbacac = 2,2,6,6-tetramethyl-3,5-heptane-dionato), was synthesised and found to have an antiferromagnetically ordered ground state with a metamagnetic phase diagram and a critical field of 0.91 T at 1.85 K. The application of a small dc field revealed the single-molecule magnet behaviour of 2, illustrating the coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization.
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesDalton Transactions
dc.subject.otherkompleksiyhdisteet
dc.subject.otherharvinaiset maametallit
dc.subject.othermagnetismi
dc.subject.othercoordination complexes
dc.subject.otherrare earth metals
dc.subject.othermagnetism
dc.titleCoexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl radical
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201711024124
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-11-02T13:15:47Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange12790-12793
dc.relation.issn1477-9226
dc.relation.numberinseries38
dc.relation.volume46
dc.type.versionacceptedVersion
dc.rights.copyright© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber282499
dc.relation.grantnumber289172
dc.subject.ysokompleksiyhdisteet
dc.subject.ysomagnetismi
dc.subject.ysoharvinaiset maametallit
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p7808
jyx.subject.urihttp://www.yso.fi/onto/yso/p15798
dc.relation.doi10.1039/C7DT02766D
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramAcademy Project, AoFen
jyx.fundinginformationThis work was supported by the Technology Industries of Finland Centennial Foundation, the Academy of Finland (projects 282499 and 289172), the University of Jyväskylä, the University of Bordeaux, the Région Aquitaine, the ANR, the CNRS, and the GdR MCM-2. We thank Lab. Tech. Elina Hautakangas for elemental analyses and Dr Anssi Peuronen for crystallographic insight.


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