Synthesis and structural studies on Ni(II) dithiocarbamates : Exploring intramolecular Ni···H-C interactions
Prakasam, B. A., Peuronen, A., Lahtinen, M., Muruganandham, M., Kolehmainen, E., Haapaniemi, E., & Sillanpää, M. (2017). Synthesis and structural studies on Ni(II) dithiocarbamates : Exploring intramolecular Ni···H-C interactions. Polyhedron, 123, 453-461. https://doi.org/10.1016/j.poly.2016.11.027
Published in
PolyhedronAuthors
Date
2017Discipline
Epäorgaaninen ja analyyttinen kemiaOrgaaninen kemiaInorganic and Analytical ChemistryOrganic ChemistryCopyright
© 2016 Elsevier Ltd. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.
Five new Ni(II) dithiocarbamates with NiS4, NiS2PN and NiS2PCl coordination spheres, viz. [Ni(bupmbzdtc)2] (1), [Ni(bupmbzdtc)(PPh3)(NCS)] (2), [Ni(bupmbzdtc)(PPh3)Cl] (3), [Ni(4-dpmpzdtc)(PPh3)Cl] (4) and [Ni(pbbzbudtc)(PPh3)(NCS)] (5), where bupmbzdtc = N-butyl(p-methylbenzyl)dithiocarbamato anion, 4-dpmpzdtc = 4-(diphenylmethyl)piperazinecarbodithioato anion, pbbzbudtc = N-(p-bromobenzyl)butyl-dithiocarbamato anion and PPh3 = triphenylphosphine, were synthesized and characterized by UV, IR, NMR and single crystal X-ray diffraction methods. Spectral results suggest a square planar geometry around the Ni(II) metal center for all the synthesized complexes. Single crystal X-ray structural analyses agree to these findings, but also show evidence of intramolecular C–H⋯Ni interactions in complexes 3 and 5 (2.801 and 2.872 Å respectively) in the solid state, analyzed further by computational (DFT) methods. Herein, these and other structural aspects of the homo- (1) and heteroleptic dithiocarbamate complexes (2–5) of Ni(II) are discussed.
...
![showless](/themes/JYX2//images/showless.png)
![showmore](/themes/JYX2//images/showmore.png)
Publisher
PergamonISSN Search the Publication Forum
0277-5387Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/26320610
Metadata
Show full item recordCollections
Related items
Showing items with similar title or keywords.
-
Synthesis, X-ray Structure, Conformational Analysis, and DFT Studies of a Giant s-Triazine bis-Schiff Base
Almarhoon, Zainab M.; Al-Zaben, Maha I.; Ben Bacha, Abir; Haukka, Matti; El-Faham, Ayman; Soliman, Saied M. (MDPI AG, 2021)The current work involves the synthesis of 2,2′-(6-(piperidin-1-yl)-1,3,5-triazine-2,4-diyl)bis(hydrazin-2-yl-1-ylidene))bis(methanylylidene))diphenol 4, characterization, and the DFT studies of the reported compound. The ... -
Coordination Complexes of a Neutral 1,2,4-Benzotriazinyl Radical Ligand: Synthesis, Molecular and Electronic Structures, and Magnetic Properties
Morgan, Ian; Mansikkamäki, Akseli; Zissimou, Georgia A.; Koutentis, Panayoitis A.; Rouzières, Mathieu; Clérac, Rodolphe; Tuononen, Heikki (Wiley - VCH Verlag GmbH & Co. KGaA, 2015)A series of d-block metal complexes of the recently reported coordinating neutral radical ligand 1-phenyl-3-(pyrid-2-yl)-1,4-dihydro-1,2,4-benzotriazin-4-yl (1) was synthesized. The investigated systems contain the ... -
Synthesis, X-ray Structure, and Hirshfeld Analysis of [Ag(3-amino-5,6-dimethyl-1,2,4-triazine)(NO3)]n : A Potent Anticancer and Antimicrobial Agent
El-Naggar, Mostafa A.; Abu-Youssef, Morsy A. M.; Haukka, Matti; Barakat, Assem; Sharaf, Mona M.; Soliman, Saied M. (MDPI AG, 2023)The [Ag(3ADMT)(NO3)]n complex was synthesized by the self-assembly of 3-amino-5,6-dimethyl-1,2,4-triazine (3ADMT) and AgNO3. Its molecular structure was analyzed utilizing FTIR spectra, elemental analysis, and single crystal ... -
Synthesis and Characterizations of Novel Isatin-s-Triazine Hydrazone Derivatives : X-ray Structure, Hirshfeld Analysis and DFT Calculations
Al-Rasheed, Hessa H.; AL-khamis, Sarah A.; Barakat, Assem; El-Faham, Ayman; Haukka, Matti; Soliman, Saied M. (MDPI AG, 2023)A novel series of isatin-s-triazine hydrazone derivatives has been synthesized and reported herein. The synthetic methodology involved the reaction of s-triazine hydrazine precursors with isatin derivatives in the presence ... -
Synthesis and Solid-State X-ray Structure of the Mononuclear Palladium(II) Complex Based on 1,2,3-Triazole Ligand
Al-Rasheed, Hessa H.; Haukka, Matti; Soliman, Saied M.; Al-Majid, Abdullah Mohammed; Ali, M.; El-Faham, Ayman; Barakat, Assem (MDPI, 2022)Herein, we described the synthesis and X-ray crystal structure of the new [Pd(3)2Cl2] complex with 1,2,3-triazole-based ligand (3). In the unit cell, there are two [Pd(3)2Cl2] molecules, and the asymmetric unit comprised ...