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dc.contributor.authorPrakasam, Balasubramaniam Arul
dc.contributor.authorPeuronen, Anssi
dc.contributor.authorLahtinen, Manu
dc.contributor.authorMuruganandham, Manickavachagam
dc.contributor.authorKolehmainen, Erkki
dc.contributor.authorHaapaniemi, Esa
dc.contributor.authorSillanpää, Mika
dc.date.accessioned2017-02-07T07:23:30Z
dc.date.available2018-11-25T22:35:26Z
dc.date.issued2017
dc.identifier.citationPrakasam, B. A., Peuronen, A., Lahtinen, M., Muruganandham, M., Kolehmainen, E., Haapaniemi, E., & Sillanpää, M. (2017). Synthesis and structural studies on Ni(II) dithiocarbamates : Exploring intramolecular Ni···H-C interactions. <i>Polyhedron</i>, <i>123</i>, 453-461. <a href="https://doi.org/10.1016/j.poly.2016.11.027" target="_blank">https://doi.org/10.1016/j.poly.2016.11.027</a>
dc.identifier.otherCONVID_26320610
dc.identifier.otherTUTKAID_71749
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/52971
dc.description.abstractFive new Ni(II) dithiocarbamates with NiS4, NiS2PN and NiS2PCl coordination spheres, viz. [Ni(bupmbzdtc)2] (1), [Ni(bupmbzdtc)(PPh3)(NCS)] (2), [Ni(bupmbzdtc)(PPh3)Cl] (3), [Ni(4-dpmpzdtc)(PPh3)Cl] (4) and [Ni(pbbzbudtc)(PPh3)(NCS)] (5), where bupmbzdtc = N-butyl(p-methylbenzyl)dithiocarbamato anion, 4-dpmpzdtc = 4-(diphenylmethyl)piperazinecarbodithioato anion, pbbzbudtc = N-(p-bromobenzyl)butyl-dithiocarbamato anion and PPh3 = triphenylphosphine, were synthesized and characterized by UV, IR, NMR and single crystal X-ray diffraction methods. Spectral results suggest a square planar geometry around the Ni(II) metal center for all the synthesized complexes. Single crystal X-ray structural analyses agree to these findings, but also show evidence of intramolecular C–H⋯Ni interactions in complexes 3 and 5 (2.801 and 2.872 Å respectively) in the solid state, analyzed further by computational (DFT) methods. Herein, these and other structural aspects of the homo- (1) and heteroleptic dithiocarbamate complexes (2–5) of Ni(II) are discussed.
dc.language.isoeng
dc.publisherPergamon
dc.relation.ispartofseriesPolyhedron
dc.subject.otherdithiocarbamate
dc.subject.otherX-ray structural analysis
dc.subject.otherNMR
dc.subject.otherC-H···Ni interaction
dc.titleSynthesis and structural studies on Ni(II) dithiocarbamates : Exploring intramolecular Ni···H-C interactions
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201701161156
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-01-16T10:15:08Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange453-461
dc.relation.issn0277-5387
dc.relation.numberinseries0
dc.relation.volume123
dc.type.versionacceptedVersion
dc.rights.copyright© 2016 Elsevier Ltd. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1016/j.poly.2016.11.027


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