Crystal structure of the borabenzene-2,6-lutidine adduct
Kivijärvi, L., & Haukka, M. (2015). Crystal structure of the borabenzene-2,6-lutidine adduct. Acta Crystallographica Section E : Crystallographic Communications, 71(12), Article o944. https://doi.org/10.1107/S2056989015020599
Date
2015Copyright
© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
In the title compound, C12H14BN, the complete molecule is
generated by a crystallographic twofold axis, with two C
atoms, the B atom and the N atom lying on the rotation axis.
The dihedral angle between the borabenzene and pyridine
rings is 81.20 (6). As well as dative electron donation from the
N atom to the B atom [B—N = 1.5659 (18) A˚ ], the methyl
substituents on the lutidine ring shield the B atom, which
further stabilizes the molecule. In the crystal, weak aromatic
– stacking between the pyridine rings [centroid–centroid
separation = 3.6268 (9) A˚ ] is observed, which generates [001]
columns of molecules.
Publisher
International Union of CrystallographyISSN Search the Publication Forum
2056-9890Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/25533647
Metadata
Show full item recordCollections
License
Except where otherwise noted, this item's license is described as © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
Related items
Showing items with similar title or keywords.
-
Crystal structure of the pyridine–diiodine (1/1) adduct
Tuikka, Matti; Haukka, Matti (International Union of Crystallography, 2015)In the title adduct, C5H5NI2, the N—I distance [2.424 (8) A˚ ] is remarkably shorter than the sum of the van der Waals radii. The line through the I atoms forms an angle of 78.39 (16) with the normal to the pyridine ring. -
Experimental and Theoretical Investigations of Tellurium(IV) Diimides and Imidotelluroxanes: X-ray Structures of B(C6F5)3 Adducts of OTe(μ-NtBu)2TeNtBu, [OTe(μ-NtBu)2Te(μ-O)]2 and tBuNH2
Schatte, Gabriele; Chivers, Tristram; Tuononen, Heikki; Suontamo, Reijo; Laitinen, Risto; Valkonen, Jussi (ACS, 2005)The hydrolysis of tBuNTe(μ-NtBu)2TeNtBu (1) with 1 or 2 equiv of (C6F5)3B·H2O results in the successive replacement of terminal imido groups by oxo ligands to give the telluroxane-Lewis acid adducts (C6F5)3B·OTe(μ-NtBu)2TeNtBu ... -
Synthesis and X-ray Structure Analysis of the Polymeric [Ag2(4-Amino-4H-1,2,4-triazole)2(NO3)]n(NO3)n Adduct : Anticancer, and Antimicrobial Applications
El-Naggar, Mostafa A.; Al-Rasheed, Hessa H.; AL-khamis, Sarah A.; El-Faham, Ayman; Abu-Youssef, Morsy A. M.; Haukka, Matti; Barakat, Assem; Sharaf, Mona M.; Soliman, Saied M. (MDPI AG, 2023)A new Ag(I) adduct was synthesized by the reaction of 4-amino-4H-1,2,4-triazole (L) with AgNO3. Its chemical structure was approved to be [Ag2(L)2(NO3)]n(NO3)n utilizing elemental analysis, FTIR spectra, and single crystal ... -
Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct
Hänninen, Mikko M.; Baldansuren, Amgalanbaatar; Pugh, Thomas (Royal Society of Chemistry, 2017)The solid and solution state structure of the vanadium(II) N‐ heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported ( SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐ en‐2‐ylidene). ... -
3D Zinc–Organic Frameworks Based on Mixed Thiophene Dicarboxylate and 4-Amino-3,5-bis(4-pyridyl)-1,2,4-triazole Linkers : Syntheses, Structural Diversity, and Single-Crystal-to-Single-Crystal Transformations
Mahajan, Shreya; Lahtinen, Manu (American Chemical Society (ACS), 2024)In this study, for the first time two new interpenetrated 3D pillared-layer metal–organic frameworks (MOFs), namely, {[Zn(bpt)(tdc)]·dmf}n (MOF-1-Zn) and {[Zn2(bpt)(tdc)2]·2(dmf)}n (MOF-2-Zn), as well as a homochiral 3D ...