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dc.contributor.authorTero, Tiia-Riikka
dc.contributor.authorSalorinne, Kirsi
dc.contributor.authorLehtivuori, Heli
dc.contributor.authorIhalainen, Janne
dc.contributor.authorNissinen, Maija
dc.date.accessioned2016-02-04T12:21:10Z
dc.date.available2016-02-04T12:21:10Z
dc.date.issued2014
dc.identifier.citationTero, T.-R., Salorinne, K., Lehtivuori, H., Ihalainen, J., & Nissinen, M. (2014). The structural diversity of benzofuran resorcinarene leads to enhanced fluorescence. <em>Chemistry - An Asian Journal</em>, 9 (7), 1860-1867. <a href="http://dx.doi.org/10.1002/asia.201402016">doi:10.1002/asia.201402016</a>
dc.identifier.otherTUTKAID_62168
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/48625
dc.description.abstractAn unexpected and previously unknown resorcinarene mono-crown with a fused benzofuran moiety in its macrocyclic core was obtained as a byproduct from a bridging reaction of tetramethoxy resorcinarene with tetraethylene glycol ditosylate. The formation of the fused benzofuran moiety in the resorcinarene macrocycle resulted in a unique rigid and puckered boat conformation, as shown by XRD studies in the solid state. Modification of the macrocycle was also observed to affect the photophysical properties in solution by enhancing the fluorescence brightness compared with a conventional resorcinarene macrocycle. The fluorescent properties enabled unique detection of structural features, that is, the rigid boat conformation with the conjugated benzofuran system and the more flexible crown bridge part, in solution.
dc.language.isoeng
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA; Chemical Research Society of India
dc.relation.ispartofseriesChemistry - An Asian Journal
dc.subject.otherbenzofuran
dc.subject.othercalixarenes
dc.subject.otherfluorescence
dc.subject.otherresorcinarenes
dc.subject.othersupramolecular chemistry
dc.subject.otherX-ray diffract
dc.titleThe structural diversity of benzofuran resorcinarene leads to enhanced fluorescence
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201602041442
dc.contributor.laitosBio- ja ympäristötieteiden laitosfi
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosThe Department of Biological and Environmental Scienceen
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineFysikaalinen kemia
dc.contributor.oppiaineOrgaaninen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2016-02-04T10:15:17Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange1860-1867
dc.relation.issn1861-471X
dc.relation.volume9
dc.type.versionacceptedVersion
dc.rights.copyright© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1002/asia.201402016


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