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dc.contributor.authorGanesamoorthy, Chelladurai
dc.contributor.authorBalakrishna, Maravanji
dc.contributor.authorMague, Joel
dc.contributor.authorTuononen, Heikki
dc.date.accessioned2015-11-20T11:04:05Z
dc.date.available2015-11-20T11:04:05Z
dc.date.issued2008
dc.identifier.citationGanesamoorthy, C., Balakrishna, M., Mague, J., & Tuononen, H. (2008). Bi-, Tetra-, and Hexanuclear AuI and Binuclear AgI Complexes and AgI Coordination Polymers Containing Phenylaminobis(phosphonite), PhN{P(OC6H4OMe-o)2}2, and Pyridyl Ligands. <i>Inorganic Chemistry</i>, <i>47</i>(7), 2764-2776. <a href="https://doi.org/10.1021/ic702133f" target="_blank">https://doi.org/10.1021/ic702133f</a>
dc.identifier.otherCONVID_18407333
dc.identifier.otherTUTKAID_33803
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47771
dc.description.abstractThe reactions of phenylaminobis(phosphonite), PhN{P(OC6H4OMe-o)2}2 (1) (PNP), with [AuCl(SMe2)] in appropriate ratios, afford the bi- and mononuclear complexes, [(AuCl)2(µ-PNP)] (2) and [(AuCl)(PNP)]2 (3) in good yield. Treatment of 2 with 2 equiv of AgX (X = OTf or ClO4) followed by the addition of 1 or 2,2′-bipyridine affords [Au2(µ-PNP)2](OTf)2 (4) and [Au2(C10H8N2)2(µ-PNP)](ClO4)2 (5), respectively. Similarly, the macrocycles [Au4(C4H4N2)2(µ-PNP)2](ClO4)4 (6), [Au4(C10H8N2)2(µ-PNP)2](ClO4)4 (7), and [Au6(C3H3N3)2(µ-PNP)3](ClO4)6 (8) are obtained by treating 2 with pyrazine, 4,4′-bipyridine, or 1,3,5-triazine in the presence of AgClO4. The reaction of 1 with AgOTf in a 1:2 molar ratio produces [Ag2(µ-OTf)2(µ-PNP)] (9). The displacement of triflate ions in 9 by 1 leads to a disubstituted derivative, [Ag2(µ-PNP)3](OTf)2 (10). The equimolar reaction of 1 with AgClO4 in THF affords [Ag2(C4H8O)2(µ-PNP)2](ClO4)2 (11). Treatment of 1 with AgClO4 followed by the addition of 2,2′-bipyridine affords a discrete binuclear complex, [Ag2(C10H8N2)2(µ-PNP)](ClO4)2 (12), whereas similar reactions with 4,4′-bipyridine or pyrazine produce one-dimensional zigzag AgI coordination polymers, [Ag2(C10H8N2)(µ-ClO4)(ClO4)(µ-PNP)]n (13) and [Ag2(C4H4N2)(µ-ClO4)(ClO4)(µ-PNP)]n (14) in good yield. The nature of metal−metal interactions in compounds 2, 4, 5, and 12 was analyzed theoretically by performing HF and CC calculations. The structures of the complexes 2, 4, 5, 7, 9, 12, and 14 are confirmed by single crystal X-ray diffraction studies.
dc.language.isoeng
dc.publisherACS
dc.relation.ispartofseriesInorganic Chemistry
dc.subject.otherfenyyliaminobisfosfoniitti
dc.subject.otherhopea- ja kultakompleksit
dc.subject.otherphenylaminobis(phosphonite)
dc.subject.otherAg- and Au complexes
dc.titleBi-, Tetra-, and Hexanuclear AuI and Binuclear AgI Complexes and AgI Coordination Polymers Containing Phenylaminobis(phosphonite), PhN{P(OC6H4OMe-o)2}2, and Pyridyl Ligands
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201511193718
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-11-19T10:15:03Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange2764-2776
dc.relation.issn0020-1669
dc.relation.numberinseries7
dc.relation.volume47
dc.type.versionacceptedVersion
dc.rights.copyright© 2008 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1021/ic702133f
dc.type.okmA1


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