Stable spirocyclic neutral radicals: aluminum and gallium boraamidinates

Chivers, Tristram; Eisler, Dana; Fedorchuk, Chantall; Schatte, Gabriele; Tuononen, Heikki; Boeré, René

doi:10.1039/B506253E

dc.contributor.author	Chivers, Tristram
dc.contributor.author	Eisler, Dana
dc.contributor.author	Fedorchuk, Chantall
dc.contributor.author	Schatte, Gabriele
dc.contributor.author	Tuononen, Heikki
dc.contributor.author	Boeré, René
dc.date.accessioned	2015-11-18T11:40:52Z
dc.date.available	2015-11-18T11:40:52Z
dc.date.issued	2005
dc.identifier.citation	Chivers, T., Eisler, D., Fedorchuk, C., Schatte, G., Tuononen, H., & Boeré, R. (2005). Stable spirocyclic neutral radicals: aluminum and gallium boraamidinates. <i>Chemical Communications</i>, (31), 3930-3932. <a href="https://doi.org/10.1039/B506253E" target="_blank">https://doi.org/10.1039/B506253E</a>
dc.identifier.other	CONVID_15539305
dc.identifier.other	TUTKAID_18178
dc.identifier.uri	https://jyx.jyu.fi/handle/123456789/47730
dc.description.abstract	Stable dark red (M = Al) or dark green (M = Ga) neutral radicals {[PhB(μ-NtBu)2]2M}˙ are obtained by the oxidation of their corresponding anions with iodine, and EPR spectra supported by DFT calculations show that the spin density is equally delocalized over all four nitrogen atoms in these spiroconjugated systems.
dc.language.iso	eng
dc.publisher	RSC
dc.relation.ispartofseries	Chemical Communications
dc.subject.other	boraamidinaatit
dc.subject.other	pysyvät radikaalit
dc.subject.other	boraamidinates
dc.subject.other	stable radicals
dc.title	Stable spirocyclic neutral radicals: aluminum and gallium boraamidinates
dc.type	article
dc.identifier.urn	URN:NBN:fi:jyu-201511183694
dc.contributor.laitos	Kemian laitos	fi
dc.contributor.laitos	Department of Chemistry	en
dc.contributor.oppiaine	Epäorgaaninen ja analyyttinen kemia	fi
dc.contributor.oppiaine	Inorganic and Analytical Chemistry	en
dc.type.uri	http://purl.org/eprint/type/JournalArticle
dc.date.updated	2015-11-18T07:15:02Z
dc.type.coar	http://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatus	peerReviewed
dc.format.pagerange	3930-3932
dc.relation.issn	1359-7345
dc.relation.numberinseries	31
dc.type.version	acceptedVersion
dc.rights.copyright	© The Royal Society of Chemistry 2005. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevel	openAccess	fi
dc.relation.doi	10.1039/B506253E
dc.type.okm	A1

Aineistoon kuuluvat tiedostot

Nimi:: stable spirocyclic neutral ...
Koko:: 769.7Kb
Tiedostomuoto:: PDF
Kuvaus:: Final Draft

Katso/Avaa

Aineisto kuuluu seuraaviin kokoelmiin

Matemaattis-luonnontieteellinen tiedekunta [5668]

Näytä suppeat kuvailutiedot

Näytetään aineistoja, joilla on samankaltainen nimeke tai asiasanat.

In Search of the [PhB(μ-NtBu)2]2As• Radical: Experimental and Computational Investigations of the Redox Chemistry of Group 15 Bis-boraamidinates

Konu, Jari; Tuononen, Heikki; Chivers, Tristram; Corrente, Andrea; Boeré, René; Roemmele, Tracey (ACS, 2008)

DFT calculations for the group 15 radicals [PhB(μ-NtBu)2]2M• (M = P, As, Sb, Bi) predict a pnictogen-centered SOMO with smaller contributions to the unpaired spin density arising from the nitrogen and boron atoms. The ...
Synthesis, X-ray structures and redox behaviour of the group 14 bis-boraamidinates M[PhB(μ-N-t-Bu)2]2 (M = Ge, Sn) and Li2M[PhB(μ-N-t-Bu)2]2 (M = Sn, Pb)

Konu, Jari; Tuononen, Heikki; Chivers, Tristram (NRC Research Press, 2009)

The solid-state structures of the complexes M[PhB(μ-N-t-Bu)2]2 (1a, M= Ge; 1b, M = Sn) were determined to be spirocyclic with two orthogonal boraamidinate (bam) ligands N,N′-chelated to the group 14 centre. Oxidation of ...
Syntheses and Structures of Magnesium and Zinc Boraamidinates: EPR and DFT Investigations of Li, Mg, Zn, B, and In Complexes of the [PhB(NtBu)2]•- Anion Radical

Chivers, Tristram; Eisler, Dana; Fedorchuk, Chantall; Schatte, Gabriele; Tuononen, Heikki (ACS, 2006)

The first magnesium and zinc boraamidinate (bam) complexes have been synthesized via metathetical reactions between dilithio bams and Grignard reagents or MCl2 (M = Mg, Zn). The following new classes of bam complexes have ...
Molecular Complexes Featuring Unsupported Dispersion-Enhanced Aluminum–Copper and Gallium–Copper Bonds

Mears, Kristian L.; Stennett, Cary R.; Taskinen, Elina K.; Knapp, Caroline E.; Carmalt, Claire J.; Tuononen, Heikki M.; Power, Philip P. (American Chemical Society (ACS), 2020)

The reaction of the copper(I) β-diketiminate copper complex {(Cu(BDIMes))2(μ-C6H6)} (BDIMes = N,N′-bis(2,4,6-trimethylphenyl)pentane-2,4-diiminate) with the low-valent group 13 metal β-diketiminates M(BDIDip) (M = Al or ...
Synthesis and Structures of Aluminum and Magnesium Complexes of Tetraimidophosphates and Trisamidothiophosphates: EPR and DFT Investigations of the Persistent Neutral Radicals {Me2Al[(μ-NR)(μ-NtBu)P(μ-NtBu)2]Li(THF)2}• (R = SiMe3, tBu)

Armstrong, Andrea; Chivers, Tristram; Tuononen, Heikki; Parvez, Masood (ACS, 2005)

Reactions of (RNH)3PNSiMe3 (3a, R = tBu; 3b, R = Cy) with trimethylaluminum result in the formation of {Me2Al(μ-NtBu)(μ-NSiMe3)P(NHtBu)2]} (4) and the dimeric trisimidometaphosphate {Me2Al[(μ-NCy)(μ-NSiMe3)P(μ-NCy)2P(μ-N ...

Stable spirocyclic neutral radicals: aluminum and gallium boraamidinates

Aineistoon kuuluvat tiedostot

Aineisto kuuluu seuraaviin kokoelmiin

Samankaltainen aineisto

In Search of the [PhB(μ-NtBu)2]2As• Radical: Experimental and Computational Investigations of the Redox Chemistry of Group 15 Bis-boraamidinates ﻿

Synthesis, X-ray structures and redox behaviour of the group 14 bis-boraamidinates M[PhB(μ-N-t-Bu)2]2 (M = Ge, Sn) and Li2M[PhB(μ-N-t-Bu)2]2 (M = Sn, Pb) ﻿

Syntheses and Structures of Magnesium and Zinc Boraamidinates: EPR and DFT Investigations of Li, Mg, Zn, B, and In Complexes of the [PhB(NtBu)2]•- Anion Radical ﻿

Molecular Complexes Featuring Unsupported Dispersion-Enhanced Aluminum–Copper and Gallium–Copper Bonds ﻿

Synthesis and Structures of Aluminum and Magnesium Complexes of Tetraimidophosphates and Trisamidothiophosphates: EPR and DFT Investigations of the Persistent Neutral Radicals {Me2Al[(μ-NR)(μ-NtBu)P(μ-NtBu)2]Li(THF)2}• (R = SiMe3, tBu) ﻿

In Search of the [PhB(μ-NtBu)2]2As• Radical: Experimental and Computational Investigations of the Redox Chemistry of Group 15 Bis-boraamidinates

Synthesis, X-ray structures and redox behaviour of the group 14 bis-boraamidinates M[PhB(μ-N-t-Bu)2]2 (M = Ge, Sn) and Li2M[PhB(μ-N-t-Bu)2]2 (M = Sn, Pb)

Syntheses and Structures of Magnesium and Zinc Boraamidinates: EPR and DFT Investigations of Li, Mg, Zn, B, and In Complexes of the [PhB(NtBu)2]•- Anion Radical

Molecular Complexes Featuring Unsupported Dispersion-Enhanced Aluminum–Copper and Gallium–Copper Bonds

Synthesis and Structures of Aluminum and Magnesium Complexes of Tetraimidophosphates and Trisamidothiophosphates: EPR and DFT Investigations of the Persistent Neutral Radicals {Me2Al[(μ-NR)(μ-NtBu)P(μ-NtBu)2]Li(THF)2}• (R = SiMe3, tBu)