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dc.contributor.authorSuhonen, Aku
dc.contributor.authorNauha, Elisa
dc.contributor.authorSalorinne, Kirsi
dc.contributor.authorHelttunen, Kaisa
dc.contributor.authorNissinen, Maija
dc.date.accessioned2012-12-04T09:50:32Z
dc.date.available2013-08-17T21:45:03Z
dc.date.issued2012fi
dc.identifier.citationSuhonen, A., Nauha, E., Salorinne, K., Helttunen, K., & Nissinen, M. (2012). Structural analysis of two foldamer-type oligoamides – the effect of hydrogen bonding on solvate formation, crystal structures and molecular conformation. <em>CrystEngComm</em>, 14 (21), 7398-7407. <a href="http://dx.doi.org/10.1039/c2ce25981h">doi:10.1039/c2ce25981h</a> Retrieved from <a href="http://pubs.rsc.org/en/content/articlelanding/2012/ce/c2ce25981h#!divAbstract">http://pubs.rsc.org/en/content/articlelanding/2012/ce/c2ce25981h#!divA...</a>fi
dc.identifier.otherTUTKAID_52296
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/40524
dc.descriptionAuthor's Final draft
dc.description.abstractThe crystal structures and molecular conformations of two foldamer-type oligoamides were analyzed. One polymorphic form and seven solvates were found for N¹,N³-bis(2-benzamidophenyl)benzene-1,3-dicarboxamide (the benzene variant), and two polymorphic forms and six solvates for N²,N⁶-bis(2-benzamidophenyl)pyridine-2,6-dicarboxamide (the pyridine variant). Three crystal structures of the benzene variant and seven structures of the pyridine variant were solved using single crystal X-ray diffraction. The crystal structures showed that the different modes of intramolecular hydrogen bonding strongly affect the conformation and folding of the molecules, which is most evidently seen with the strongly folded helical structure of the pyridine variant. NOESY experiments suggest that the intramolecular hydrogen bonding is stable enough to retain a folded or partially folded conformation even in solution.fi
dc.language.isoeng
dc.publisherRSC Publishing
dc.relation.ispartofseriesCrystEngComm
dc.relation.urihttp://pubs.rsc.org/en/content/articlelanding/2012/ce/c2ce25981h#!divAbstract
dc.subject.otherfoldameeri
dc.subject.otheroligoamidi
dc.subject.otherkristallografia
dc.subject.otherfoldamer
dc.subject.otheroligoamide
dc.subject.othercrystallography
dc.titleStructural analysis of two foldamer-type oligoamides the effect of hydrogen bonding on solvate formation, crystal structures and molecular conformation
dc.typeArticle
dc.identifier.urnURN:NBN:fi:jyu-201211293120
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.type.urihttp://purl.org/eprint/type/SubmittedJournalArticle
dc.identifier.doi10.1039/c2ce25981h
dc.date.updated2012-11-29T10:39:43Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange7398-7407
dc.relation.issn1466-8033
dc.relation.numberinseries21
dc.relation.volume14
dc.type.versionacceptedVersion
dc.rights.copyright© Royal Society of Chemistry. This is an author's final draft version of an article whose final and definitive form has been published by RSC.
dc.rights.accesslevelopenAccessfi


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