N²,N²,N⁶,N⁶-Tetrakis(2,3,4,5,6-perfluorobenzoyl)-2,6-diaminopyridine

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dc.contributor.author Valkonen, Arto
dc.contributor.author Kolehmainen, Erkki
dc.contributor.author Osmialowski, Borys
dc.date.accessioned 2011-12-19T10:45:21Z
dc.date.available 2011-12-19T10:45:21Z
dc.date.issued 2011
dc.identifier.citation Valkonen, A., Kolehmainen, E. & Osmialowski, B. (2011). N²,N²,N⁶,N⁶-Tetrakis(2,3,4,5,6-perfluorobenzoyl)-2,6-diaminopyridine. Acta Crystallographica Section E: Structure Reports Online , E67 (12), o3429-o3430. doi:10.1107/S1600536811048768
dc.identifier.issn 1600-5368
dc.identifier.other TUTKAID_47707
dc.identifier.uri http://hdl.handle.net/123456789/37112
dc.description.abstract The title compound, C³³H³F²⁰N³O⁴, is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diaminopyridine with 2,3,4,5,6-pentafluorobenzoyl chloride in a 1:2 molar ratio. The molecule is located on a twofold axis and one of its symmetry-independent 2,3,4,5,6-pentafluorobenzoyl groups is disordered over two sets of sites, the occupancy of the major component being 0.773 (3). In the major component, the dihedral angle between the perfluorophenyl groups is 63.64 (10)°, and these groups form dihedral angles of 67.14 (7) and 21.1 (2)° with the pyridine core. Short intermolecular C-HO and C-H...N contacts are found in the crystal structure.
dc.language.iso eng
dc.publisher IuCr
dc.relation.ispartof Acta Crystallographica Section E: Structure Reports Online
dc.relation.uri http://journals.iucr.org/e/issues/2011/12/00/issconts.html
dc.subject.other kiderakenne en
dc.subject.other röntgenrakenne en
dc.subject.other Crystal structure en
dc.subject.other X-ray structure en
dc.title N²,N²,N⁶,N⁶-Tetrakis(2,3,4,5,6-perfluorobenzoyl)-2,6-diaminopyridine
dc.type Article en
dc.identifier.urn URN:NBN:fi:jyu-2011121511803
dc.subject.kota 116
dc.contributor.laitos Department of Chemistry en
dc.contributor.laitos Kemian laitos fi
dc.contributor.oppiaine orgaaninen kemia fi
jyx.tutka.volyme E67
jyx.tutka.mnumber 12
jyx.tutka.pagetopage o3429-o3430
dc.type.uri http://purl.org/eprint/type/JournalArticle
dc.identifier.doi 10.1107/S1600536811048768
dc.date.updated 2011-12-15T04:30:06Z
dc.description.version Publisher's PDF
eprint.status http://purl.org/eprint/type/status/PeerReviewed

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