cis,cis,cis-(Acetato-k²O,O´)bis[1,2-bis- (diphenylphosphanyl)ethane-k²P,P´]- ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride
Figueira, J., Rodrigues, J., & Valkonen, A. (2013). cis,cis,cis-(Acetato-k²O,O´)bis[1,2-bis- (diphenylphosphanyl)ethane-k²P,P´]- ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride. Acta Crystallographica Section E: Structure Reports Online, E69 (4), m226. doi:10.1107/S160053681300737X Retrieved from http://journals.iucr.org/e/issues/2013/04/00/zs2249/index.html
In the title RuII carboxylate compound, [Ru(C₂H₃O₂)(C₂₆H₂₄P₂)₂](CF₃O₃S)₀.₇₅Cl₀.₂₅, the distorted tris-bidentate octahedral stereochemistry about the RuII atom in the complex cation comprises four P-atom donors from two 1,2-bis(diphenylphosphanyl)ethane ligands [Ru-P = 2.2881 (13)-2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru-O = 2.191 (3) and 2.202 (3) Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoromethanesulfonate anions and one chloride anion, with two such formula units in the unit cell.
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