Iodine(I) pnictogenate complexes as Iodination reagents
| dc.contributor.author | Mohan, Sharath | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Ward, Jas S. | |
| dc.date.accessioned | 2024-08-01T11:00:26Z | |
| dc.date.available | 2024-08-01T11:00:26Z | |
| dc.date.issued | 2024 | |
| dc.identifier.citation | Mohan, S., Rissanen, K., & Ward, J. S. (2024). Iodine(I) pnictogenate complexes as Iodination reagents. <i>Communications Chemistry</i>, <i>7</i>, Article 159. <a href="https://doi.org/10.1038/s42004-024-01240-0" target="_blank">https://doi.org/10.1038/s42004-024-01240-0</a> | |
| dc.identifier.other | CONVID_221136037 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/96474 | |
| dc.description.abstract | Halogen(I) complexes are widely used as halogenation reagents and traditionally feature homoleptic stabilising Lewis bases, though the recent revitalisation of iodine(I) carboxylate chemistry has provided isolable examples of heteroleptic iodine(I) complexes. This work reports iodine(I) pnictogenate complexes stabilised by a Lewis base (L), Ph2P(O)O─I─L, synthesised via cation exchange from the silver(I) precursor, (Ph2P(O)OAg)n. The complexes were characterised in both solution (1H, 1H-15N HMBC, 31P) and the solid state, and supplemented computationally by DFT studies. Interestingly, these iodine(I) pnictogenates demonstrate a range of stabilities, and have been found to excel as iodination reagents in comparison to carbonyl hypoiodites, with comparable reactivity to the eponymous Barluenga’s reagent in the iodination of antipyrine. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Nature Publishing Group | |
| dc.relation.ispartofseries | Communications Chemistry | |
| dc.rights | CC BY 4.0 | |
| dc.title | Iodine(I) pnictogenate complexes as Iodination reagents | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202408015295 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.relation.issn | 2399-3669 | |
| dc.relation.volume | 7 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2024 the Authors | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.grantnumber | 351121 | |
| dc.relation.grantnumber | 356187 | |
| dc.subject.yso | kompleksiyhdisteet | |
| dc.subject.yso | jodi | |
| dc.subject.yso | reagenssit | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p18902 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p15893 | |
| dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
| dc.relation.doi | 10.1038/s42004-024-01240-0 | |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Suomen Akatemia | fi |
| dc.relation.funder | Suomen Akatemia | fi |
| jyx.fundingprogram | Academy Project, AoF | en |
| jyx.fundingprogram | Academy Research Fellow, AoF | en |
| jyx.fundingprogram | Akatemiahanke, SA | fi |
| jyx.fundingprogram | Akatemiatutkija, SA | fi |
| jyx.fundinginformation | K.R. and J.S.W. gratefully acknowledge the Research Council of Finland (formerly the Academy of Finland, grant numbers 351121 and 356187, respectively) for funding. | |
| dc.type.okm | A1 |
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