Experimental and theoretical studies on some quinone and quinol radicals
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Theoretical and experimental studies of some main group compounds : from closed shell interactions to singlet diradicals and stable radicals
Moilanen, Jani (University of Jyväskylä, 2012)Acquiring knowledge of different interactions within and between molecules is a fascinating undertaking as it not only deepens our understanding of chemical bonding but also offers insight into electronic structures, ... -
Experimental and Theoretical Investigations of Tellurium(IV) Diimides and Imidotelluroxanes: X-ray Structures of B(C6F5)3 Adducts of OTe(μ-NtBu)2TeNtBu, [OTe(μ-NtBu)2Te(μ-O)]2 and tBuNH2
Schatte, Gabriele; Chivers, Tristram; Tuononen, Heikki; Suontamo, Reijo; Laitinen, Risto; Valkonen, Jussi (ACS, 2005)The hydrolysis of tBuNTe(μ-NtBu)2TeNtBu (1) with 1 or 2 equiv of (C6F5)3B·H2O results in the successive replacement of terminal imido groups by oxo ligands to give the telluroxane-Lewis acid adducts (C6F5)3B·OTe(μ-NtBu)2TeNtBu ... -
Experimental and Theoretical Investigations of the Contact Ion Pairs Formed by Reactions of the Anions [(EPR2)2N]− (R = iPr, tBu; E = S, Se) with the Cations [(TePR2)2N]+ (R = iPr, tBu)
Robertson, Stuart; Chivers, Tristram; Tuononen, Heikki (ACS, 2009)Reactions of the sodium salts [(EPR2)2N]Na(TMEDA) (R = iPr, tBu; E = S, Se) with the iodide salts [(TePR2)2N]I (R = iPr, tBu) in toluene produce the mixed-chalcogen systems [(EPR2)2N][(TePR2)2N] (6b, E = Se, R = tBu; 6c, ... -
Experimental and Theoretical Investigations of the Redox Behavior of the Heterodichalcogenido Ligands [(EPiPr2)(TePiPr2)N]− (E = S, Se): Cyclic Cations and Acyclic Dichalcogenide Dimers
Robertson, Stuart; Chivers, Tristram; Tuononen, Heikki (ACS, 2008)The two-electron oxidation of the lithium salts of the heterodichalcogenidoimidodiphosphinate anions [(EPiPr2)(TePiPr2)N]− (1a, E = S; 1b, E = Se) with iodine yields cyclic cations [(EPiPr2)(TePiPr2)N]+ as their iodide ... -
The impact of ortho‐substituents on Bonding in Silver(I) and Halogen(I) complexes of 2‐Mono‐ and 2,6‐Disubstituted Pyridines : An In‐depth Experimental and Theoretical Study
Kumar, Parveen; Rautiainen, J. Mikko; Novotny, Jan; Ward, Jas S.; Marek, Radek; Rissanen, Kari; Puttreddy, Rakesh (Wiley, 2024)The coordination nature of 2-mono- and 2,6-disubstituted pyridines with electron-withdrawing halogen and electron-donating methyl groups for [N–X–N]⁺ (X =I, Br) complexations have been studied using 15N NMR, X-ray ...