dc.contributor.author | Marin, Riccardo | |
dc.contributor.author | Alves Gálico, Diogo | |
dc.contributor.author | Gayfullina, Rezeda | |
dc.contributor.author | Moilanen, Jani O. | |
dc.contributor.author | Carlos, Luís D. | |
dc.contributor.author | Jaque, Daniel | |
dc.contributor.author | Murugesu, Muralee | |
dc.date.accessioned | 2023-12-04T10:06:43Z | |
dc.date.available | 2023-12-04T10:06:43Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Marin, R., Alves Gálico, D., Gayfullina, R., Moilanen, J. O., Carlos, L. D., Jaque, D., & Murugesu, M. (2022). A zero-field single-molecule magnet with luminescence thermometry capabilities containing soft donors. <i>Journal of Materials Chemistry C</i>, <i>10</i>(37), 13946-13953. <a href="https://doi.org/10.1039/d2tc01661c" target="_blank">https://doi.org/10.1039/d2tc01661c</a> | |
dc.identifier.other | CONVID_148801629 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/92194 | |
dc.description.abstract | Simultaneous fine-tune of magnetic and optical properties in lanthanide single-molecule magnets (SMMs) is a daunting task. Even more so when additional functionalities, like luminescence thermometry, are sought after. Herein, we explore the use of a ligand with both soft and hard donor atoms (thiobenzoate, tba−) as a strategy to prepare a multifunctional optomagnetic lanthanide complex. The proposed mononuclear Dy3+ complex acts as a zero-field SMM, whose energy barrier to magnetization reversal was confirmed from the analysis of the photoluminescence spectrum. Moreover, the temperature dependence of the emission spectral profile was harnessed to build a thermometric approach working below 12 K – where the complex behaves as an SMM. In search for general trends informing the preparation of similar multifunctional SMMs, we modelled the electronic properties of a series of complexes where the sulfur atom of tba− is replaced for other chalcogens (O, Se, Te). These calculations show that careful choice of ligands with soft donor atoms can boost both magnetic and thermometric performances, paving the way for the rational design of novel multifunctional lanthanide complexes. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry (RSC) | |
dc.relation.ispartofseries | Journal of Materials Chemistry C | |
dc.rights | In Copyright | |
dc.title | A zero-field single-molecule magnet with luminescence thermometry capabilities containing soft donors | |
dc.type | research article | |
dc.identifier.urn | URN:NBN:fi:jyu-202312048191 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 13946-13953 | |
dc.relation.issn | 2050-7526 | |
dc.relation.numberinseries | 37 | |
dc.relation.volume | 10 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © The Royal Society of Chemistry 2022 | |
dc.rights.accesslevel | openAccess | fi |
dc.type.publication | article | |
dc.relation.grantnumber | 315829 | |
dc.relation.grantnumber | 320015 | |
dc.relation.grantnumber | 345484 | |
dc.subject.yso | molekyylit | |
dc.subject.yso | luminesenssi | |
dc.subject.yso | magneettiset ominaisuudet | |
dc.subject.yso | kompleksiyhdisteet | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p2984 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p1646 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p597 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
dc.relation.doi | 10.1039/d2tc01661c | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
jyx.fundingprogram | Academy Research Fellow, AoF | en |
jyx.fundingprogram | Research costs of Academy Research Fellow, AoF | en |
jyx.fundingprogram | Research costs of Academy Research Fellow, AoF | en |
jyx.fundingprogram | Akatemiatutkija, SA | fi |
jyx.fundingprogram | Akatemiatutkijan tutkimuskulut, SA | fi |
jyx.fundingprogram | Akatemiatutkijan tutkimuskulut, SA | fi |
jyx.fundinginformation | J. O. M. and R. G. acknowledge Academy of Finland (project numbers 315829, 320015, and 345484) for funding | |
dc.type.okm | A1 | |