Show simple item record

dc.contributor.authorHommelsheim, Renè
dc.contributor.authorvan Nahl, Robin
dc.contributor.authorHanek, Lena M.
dc.contributor.authorWard, Jas S.
dc.contributor.authorRissanen, Kari
dc.contributor.authorBolm, Carsten
dc.date.accessioned2023-11-16T12:49:42Z
dc.date.available2023-11-16T12:49:42Z
dc.date.issued2024
dc.identifier.citationHommelsheim, R., van Nahl, R., Hanek, L. M., Ward, J. S., Rissanen, K., & Bolm, C. (2024). Palladium‐Catalyzed Domino Reaction for the Synthesis of 3‐Amino 1,2,4‐Benzothiadiazine 1,1‐Dioxides. <i>Advanced Synthesis and Catalysis</i>, <i>366</i>(4), 717-724. <a href="https://doi.org/10.1002/adsc.202300875" target="_blank">https://doi.org/10.1002/adsc.202300875</a>
dc.identifier.otherCONVID_194431999
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/91943
dc.description.abstractA palladium‐catalyzed domino reaction of 2‐azidosulfonamides and isocyanides enables the synthesis of 3‐amino‐substituted 1,2,4‐benzothiadiazine 1,1‐dioxides at room temperature. By applying commercially available Pd(dba)2 in catalyst loadings as low as 1.0 mol%, a variety of 21 differently substituted 2H‐1,2,4‐benzothiadiazine 1,1‐dioxides can be prepared within 2 h. Moreover, the developed protocol gives access to the related 4H heterocycles.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAdvanced Synthesis and Catalysis
dc.rightsCC BY 4.0
dc.subject.otherdominoreactions
dc.subject.otherpalladiumcatalysis
dc.subject.othersulfur heterocycles
dc.subject.othersulfonamides
dc.subject.otherazides
dc.titlePalladium‐Catalyzed Domino Reaction for the Synthesis of 3‐Amino 1,2,4‐Benzothiadiazine 1,1‐Dioxides
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202311167961
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange717-724
dc.relation.issn1615-4150
dc.relation.numberinseries4
dc.relation.volume366
dc.type.versionpublishedVersion
dc.rights.copyright© 2023 the Authors
dc.rights.accesslevelopenAccessfi
dc.format.contentfulltext
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1002/adsc.202300875
jyx.fundinginformationFondsder Chemischen Industriee.V. (Kekulé scholarship) and Friedrich-Ebert-Stiftung (Promotionsförderung) are acknowledged for supporting the doctoral studies of RH. The authors thank Benjamin James Statham (RWTH Aachen University) for critical proof reading and fruitful discussion. We thank Mrs. Susanne Pohlman for her support with the synthesis of starting materials, Marcus Frings for the measurement and analysis of HPLC samples, and Dr. Wolfgang Bettray for MS analyses and helpful discussion (all three RWTH Aachen University). In addition, we acknowledge the Alexander von Humboldt Foundation for support of K. R. (AvH research award).
dc.type.okmA1


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

CC BY 4.0
Except where otherwise noted, this item's license is described as CC BY 4.0