Mechanochemical Difluoromethylations of Alcohols
| dc.contributor.author | van Bonn, Pit | |
| dc.contributor.author | Ke, Jinbo | |
| dc.contributor.author | Weike, Christopher | |
| dc.contributor.author | Ward, Jas S. | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Bolm, Carsten | |
| dc.date.accessioned | 2023-08-24T04:51:25Z | |
| dc.date.available | 2023-08-24T04:51:25Z | |
| dc.date.issued | 2023 | |
| dc.identifier.citation | van Bonn, P., Ke, J., Weike, C., Ward, J. S., Rissanen, K., & Bolm, C. (2023). Mechanochemical Difluoromethylations of Alcohols. <i>CCS chemistry</i>, <i>5</i>(8), 1737-1744. <a href="https://doi.org/10.31635/ccschem.023.202302783" target="_blank">https://doi.org/10.31635/ccschem.023.202302783</a> | |
| dc.identifier.other | CONVID_184109461 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/88648 | |
| dc.description.abstract | Difluoromethyl ethers are formed through mechanochemical reactions of alcohols with difluorocarbene in a mixer mill. The protocol could be applied to primary, secondary, and tertiary alcohols, yielding the corresponding products in excellent yields (up to 99%) after 1 h reaction time at room temperature. The transformations proceeded under solvent-free reaction conditions, followed by product purification by filtration, which drastically reduced the amount of waste generated during the process. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Chinese Chemical Society | |
| dc.relation.ispartofseries | CCS chemistry | |
| dc.rights | CC BY-NC 3.0 | |
| dc.subject.other | mechanochemistry | |
| dc.subject.other | ball milling | |
| dc.subject.other | solvent-free reaction | |
| dc.subject.other | difluorocarbene | |
| dc.subject.other | difluoromethyl ether | |
| dc.title | Mechanochemical Difluoromethylations of Alcohols | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202308244740 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Orgaaninen kemia | fi |
| dc.contributor.oppiaine | Organic Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 1737-1744 | |
| dc.relation.issn | 2096-5745 | |
| dc.relation.numberinseries | 8 | |
| dc.relation.volume | 5 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © Authors | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.subject.yso | alkoholit (yhdisteet) | |
| dc.subject.yso | kemialliset reaktiot | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p5845 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p3658 | |
| dc.rights.url | https://creativecommons.org/licenses/by-nc/3.0/ | |
| dc.relation.doi | 10.31635/ccschem.023.202302783 | |
| jyx.fundinginformation | This research was made possible by the generous support of the Rhine-Westphalia Technical University of Aachen (RWTH Aachen University). We also acknowledge the Alexander von Humboldt Foundation for support of K. R. (AvH research award). | |
| dc.type.okm | A1 |
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