Expansion and Compression of a Helicate with Central Diol-Units as Stereocontrolling Moieties
Grüninger, S., Mevissen, C., Ward, J. S., Rissanen, K., & Albrecht, M. (2022). Expansion and Compression of a Helicate with Central Diol-Units as Stereocontrolling Moieties. Organic Materials, 4(4), 277-280. https://doi.org/10.1055/a-1945-0582
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Organic MaterialsDate
2022Copyright
© 2022. The Author(s)
The dicatechol ester ligand 2-H4 forms the compressed helicate Li4[(2)3Ti2] which upon removal of the internally bound lithium cations expands. In the compressed form, the chiral diol units control the stereochemistry of the complex which is lost upon expansion of the system.
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Georg Thieme Verlag KGISSN Search the Publication Forum
2625-1825Keywords
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https://converis.jyu.fi/converis/portal/detail/Publication/156553713
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This study has been supported by the Deutsche Forschungsgemeinschaft (Al 410/37-1).License
Except where otherwise noted, this item's license is described as CC BY-NC-ND 4.0