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dc.contributor.authorAl-Rasheed, Hessa H.
dc.contributor.authorHaukka, Matti
dc.contributor.authorSoliman, Saied M.
dc.contributor.authorAl-Majid, Abdullah Mohammed
dc.contributor.authorAli, M.
dc.contributor.authorEl-Faham, Ayman
dc.contributor.authorBarakat, Assem
dc.date.accessioned2022-12-13T09:27:01Z
dc.date.available2022-12-13T09:27:01Z
dc.date.issued2022
dc.identifier.citationAl-Rasheed, H. H., Haukka, M., Soliman, S. M., Al-Majid, A. M., Ali, M., El-Faham, A., & Barakat, A. (2022). Synthesis and Solid-State X-ray Structure of the Mononuclear Palladium(II) Complex Based on 1,2,3-Triazole Ligand. <i>Crystals</i>, <i>12</i>(10), Article 1335. <a href="https://doi.org/10.3390/cryst12101335" target="_blank">https://doi.org/10.3390/cryst12101335</a>
dc.identifier.otherCONVID_164362793
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/84323
dc.description.abstractHerein, we described the synthesis and X-ray crystal structure of the new [Pd(3)2Cl2] complex with 1,2,3-triazole-based ligand (3). In the unit cell, there are two [Pd(3)2Cl2] molecules, and the asymmetric unit comprised half of this formula due to the presence of an inversion symmetry element at the Pd(II) center. The monoclinic unit cell volume is 1327.85(6) Å3, with crystal parameters of a = 10.7712(2) Å, b = 6.8500(2) Å, and c = 18.2136(6) Å, while β = 98.851(2)°. The structure comprised two trans triazole ligand units coordinated to the Pd(II) ion via one of the N-atoms of the triazole moiety. In addition, the Pd(II) is further coordinated with two trans chloride groups, where each of the trans bonds is equidistant. The crystal structure of the [Pd(3)2Cl2] complex was compared with that for free triazole ligand 3. It was found that the coordinated ligand showed less twist around the C–N bond compared to free triazole ligand 3. The molecular packing of the latter is found controlled by short O…H, N…H, C…N, and C…C interactions in addition to the short Cl…F interhalogen and π–π interactions. H…H (23.5%), Cl…H (14.4%), N…H (14.3%), and O…H (11.2%) are the most dominant contacts. In the [Pd(3)2Cl2] complex, no significant interhalogen or π–π interactions were detected. In this case, Cl…H (31.1%), H…H (16.7%), O…H (11.6%), and F…H (9.7%) are the most dominant contacts.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherMDPI
dc.relation.ispartofseriesCrystals
dc.rightsCC BY 4.0
dc.subject.other1,2,3-triazole ligand
dc.subject.otherPd(II)-complex
dc.subject.otherHirshfeld
dc.subject.otherX-ray
dc.subject.otherintermolecular interactions
dc.titleSynthesis and Solid-State X-ray Structure of the Mononuclear Palladium(II) Complex Based on 1,2,3-Triazole Ligand
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202212135580
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineInorganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.relation.issn2073-4352
dc.relation.numberinseries10
dc.relation.volume12
dc.type.versionpublishedVersion
dc.rights.copyright© 2022 by the authors. Licensee MDPI, Basel, Switzerland.
dc.rights.accesslevelopenAccessfi
dc.subject.ysoröntgenkristallografia
dc.subject.ysopalladium
dc.subject.ysokemiallinen synteesi
dc.subject.ysokompleksiyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p29058
jyx.subject.urihttp://www.yso.fi/onto/yso/p26929
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.3390/cryst12101335
jyx.fundinginformationThe authors would like to extend their sincere appreciation to the Researchers Supporting Project (RSP-2021/64), King Saud University, Riyadh, Saudi Arabia.
dc.type.okmA1


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