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dc.contributor.authorMattsson, Ida
dc.contributor.authorLahtinen, Manu
dc.contributor.authorSitdikov, Ruzal
dc.contributor.authorWank, Bianca
dc.contributor.authorSaloranta-Simell, Tiina
dc.contributor.authorLeino, Reko
dc.date.accessioned2022-06-22T11:23:21Z
dc.date.available2022-06-22T11:23:21Z
dc.date.issued2022
dc.identifier.citationMattsson, I., Lahtinen, M., Sitdikov, R., Wank, B., Saloranta-Simell, T., & Leino, R. (2022). Phase-selective low molecular weight organogelators derived from allylated D-mannose. <i>Carbohydrate research</i>, <i>518</i>, Article 108596. <a href="https://doi.org/10.1016/j.carres.2022.108596" target="_blank">https://doi.org/10.1016/j.carres.2022.108596</a>
dc.identifier.otherCONVID_146536424
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/81974
dc.description.abstractIn the last decades, synthesis and design of low molecular weight organogelators has gained increasing attention due to their versatile use in, for example, cosmetics, biomedicine and oil spill remediation. In this work, three potential gelators have been prepared from allylated d-mannose. Both the gelators and the corresponding gels formed were thoroughly characterized by crystallography, FTIR spectroscopy, SEM, rheometry and NMR spectroscopy, in solution and in solid state. The results showed that two of the compounds phase-selectively form gels with hydrocarbon solvents. The most promising gelator compound is alkene terminated, with the unsaturated end functionality not critical for gel formation, tentatively providing the possibility for customizing the gelation properties by further chemical modification. Alternatively, the alkene group could possibly be utilized as a linker for future coupling to carrier materials or surfaces to further increase the mechanical strength of the gel.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherElsevier BV
dc.relation.ispartofseriesCarbohydrate research
dc.rightsCC BY 4.0
dc.subject.otherD-mannoosi
dc.subject.otherLMWOG
dc.subject.othergels
dc.subject.otherD-mannose
dc.subject.otherphase selectivity
dc.subject.othersolid state NMR spectroscop
dc.titlePhase-selective low molecular weight organogelators derived from allylated D-mannose
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202206223579
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineResurssiviisausyhteisöfi
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic Chemistryen
dc.contributor.oppiaineSchool of Resource Wisdomen
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.relation.issn0008-6215
dc.relation.volume518
dc.type.versionpublishedVersion
dc.rights.copyright© 2022 The Authors. Published by Elsevier Ltd.
dc.rights.accesslevelopenAccessfi
dc.subject.ysohiilihydraatit
dc.subject.ysomonosakkaridit
dc.subject.ysogeelit
dc.subject.ysoinfrapunaspektroskopia
dc.subject.ysohyötykäyttö
dc.subject.ysokidetiede
dc.subject.ysoNMR-spektroskopia
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p7171
jyx.subject.urihttp://www.yso.fi/onto/yso/p24524
jyx.subject.urihttp://www.yso.fi/onto/yso/p12973
jyx.subject.urihttp://www.yso.fi/onto/yso/p38871
jyx.subject.urihttp://www.yso.fi/onto/yso/p2181
jyx.subject.urihttp://www.yso.fi/onto/yso/p643
jyx.subject.urihttp://www.yso.fi/onto/yso/p26254
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.datasethttps://dx.doi.org/10.5517/ccdc.csd.cc2b4qfn
dc.relation.doi10.1016/j.carres.2022.108596
jyx.fundinginformationIM gratefully acknowledges the Society of Swedish Literature in Finland for funding.


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