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dc.contributor.authorWilcox, Scott
dc.contributor.authorSethio, Daniel
dc.contributor.authorWard, Jas S
dc.contributor.authorFrontera, Antonio
dc.contributor.authorLindh, Roland
dc.contributor.authorRissanen, Kari
dc.contributor.authorErdelyi, Mate
dc.date.accessioned2022-04-20T08:43:19Z
dc.date.available2022-04-20T08:43:19Z
dc.date.issued2022
dc.identifier.citationWilcox, S., Sethio, D., Ward, J. S., Frontera, A., Lindh, R., Rissanen, K., & Erdelyi, M. (2022). Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?. <i>Chemical Communications</i>, <i>58</i>(32), 4977-4980. <a href="https://doi.org/10.1039/D2CC00994C" target="_blank">https://doi.org/10.1039/D2CC00994C</a>
dc.identifier.otherCONVID_117600897
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/80629
dc.description.abstractThe interaction of a [bis(pyridine)iodine(I)]+ cation with a [bis(pyridine)silver(I)]+ cation, in which an iodonium ion acts as nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. No measurable interaction is observed between the cationic species in solution by NMR; DFT reveals that if there is an attractive interaction between this complexes in solution, it is dominantly the π-π interaction of pyridinesen
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.ispartofseriesChemical Communications
dc.rightsCC BY 3.0
dc.titleDo 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202204202312
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange4977-4980
dc.relation.issn1359-7345
dc.relation.numberinseries32
dc.relation.volume58
dc.type.versionpublishedVersion
dc.rights.copyright© 2022 The Royal Society of Chemistry
dc.rights.accesslevelopenAccessfi
dc.subject.ysokidetiede
dc.subject.ysokemialliset yhdisteet
dc.subject.ysohopea
dc.subject.ysojodi
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p643
jyx.subject.urihttp://www.yso.fi/onto/yso/p324
jyx.subject.urihttp://www.yso.fi/onto/yso/p7409
jyx.subject.urihttp://www.yso.fi/onto/yso/p18902
dc.rights.urlhttps://creativecommons.org/licenses/by/3.0/
dc.relation.doi10.1039/D2CC00994C
jyx.fundinginformationThis work was supported by Vetenskapsrådet [2020-03431; 2020-03182] and made use of the NMR Uppsala infrastructure, which is funded by the Department of Chemistry – BMC and the Disciplinary Domain of Medicine and Pharmacy. The computations were enabled by resources provided by the Swedish National Infrastructure for Computing (SNIC) through project SNIC 2021-5-359.


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