Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?
| dc.contributor.author | Wilcox, Scott | |
| dc.contributor.author | Sethio, Daniel | |
| dc.contributor.author | Ward, Jas S | |
| dc.contributor.author | Frontera, Antonio | |
| dc.contributor.author | Lindh, Roland | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Erdelyi, Mate | |
| dc.date.accessioned | 2022-04-20T08:43:19Z | |
| dc.date.available | 2022-04-20T08:43:19Z | |
| dc.date.issued | 2022 | |
| dc.identifier.citation | Wilcox, S., Sethio, D., Ward, J. S., Frontera, A., Lindh, R., Rissanen, K., & Erdelyi, M. (2022). Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?. <i>Chemical Communications</i>, <i>58</i>(32), 4977-4980. <a href="https://doi.org/10.1039/D2CC00994C" target="_blank">https://doi.org/10.1039/D2CC00994C</a> | |
| dc.identifier.other | CONVID_117600897 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/80629 | |
| dc.description.abstract | The interaction of a [bis(pyridine)iodine(I)]+ cation with a [bis(pyridine)silver(I)]+ cation, in which an iodonium ion acts as nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. No measurable interaction is observed between the cationic species in solution by NMR; DFT reveals that if there is an attractive interaction between this complexes in solution, it is dominantly the π-π interaction of pyridines | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry (RSC) | |
| dc.relation.ispartofseries | Chemical Communications | |
| dc.rights | CC BY 3.0 | |
| dc.title | Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution? | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202204202312 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Orgaaninen kemia | fi |
| dc.contributor.oppiaine | Organic Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 4977-4980 | |
| dc.relation.issn | 1359-7345 | |
| dc.relation.numberinseries | 32 | |
| dc.relation.volume | 58 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2022 The Royal Society of Chemistry | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.subject.yso | kidetiede | |
| dc.subject.yso | kemialliset yhdisteet | |
| dc.subject.yso | hopea | |
| dc.subject.yso | jodi | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p643 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p324 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p7409 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p18902 | |
| dc.rights.url | https://creativecommons.org/licenses/by/3.0/ | |
| dc.relation.doi | 10.1039/D2CC00994C | |
| jyx.fundinginformation | This work was supported by Vetenskapsrådet [2020-03431; 2020-03182] and made use of the NMR Uppsala infrastructure, which is funded by the Department of Chemistry – BMC and the Disciplinary Domain of Medicine and Pharmacy. The computations were enabled by resources provided by the Swedish National Infrastructure for Computing (SNIC) through project SNIC 2021-5-359. | |
| dc.type.okm | A1 |
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