Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
| dc.contributor.author | Ward, Jas S. | |
| dc.contributor.author | Gomila, Rosa M. | |
| dc.contributor.author | Frontera, Antonio | |
| dc.contributor.author | Rissanen, Kari | |
| dc.date.accessioned | 2022-03-24T11:49:24Z | |
| dc.date.available | 2022-03-24T11:49:24Z | |
| dc.date.issued | 2022 | |
| dc.identifier.citation | Ward, J. S., Gomila, R. M., Frontera, A., & Rissanen, K. (2022). Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines. <i>RSC Advances</i>, <i>12</i>(14), 8674-8682. <a href="https://doi.org/10.1039/d2ra01390h" target="_blank">https://doi.org/10.1039/d2ra01390h</a> | |
| dc.identifier.other | CONVID_117399984 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/80363 | |
| dc.description.abstract | The silver(I) and iodine(I) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(I) complex formation. The complexes were characterised by 1H and 1H–15N HMBC NMR, X-ray crystallography, and DFT calculations. The solid-state structures for the silver(I) and iodine(I) complexes were extensively compared to the literature and analysed by DFT to examine the influence of the sterically bulky pyridines and their anions. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry (RSC) | |
| dc.relation.ispartofseries | RSC Advances | |
| dc.rights | CC BY-NC 3.0 | |
| dc.title | Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202203242050 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Orgaaninen kemia | fi |
| dc.contributor.oppiaine | Organic Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 8674-8682 | |
| dc.relation.issn | 2046-2069 | |
| dc.relation.numberinseries | 14 | |
| dc.relation.volume | 12 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2022 The Author(s). Published by the Royal Society of Chemistry | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.relation.grantnumber | 317259 | |
| dc.subject.yso | hopea | |
| dc.subject.yso | röntgenkristallografia | |
| dc.subject.yso | kemia | |
| dc.subject.yso | supramolekulaarinen kemia | |
| dc.subject.yso | kemialliset yhdisteet | |
| dc.subject.yso | jodi | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p7409 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p29058 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p1801 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p37759 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p324 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p18902 | |
| dc.rights.url | https://creativecommons.org/licenses/by-nc/3.0/ | |
| dc.relation.doi | 10.1039/d2ra01390h | |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Suomen Akatemia | fi |
| jyx.fundingprogram | Academy Project, AoF | en |
| jyx.fundingprogram | Akatemiahanke, SA | fi |
| jyx.fundinginformation | The authors gratefully acknowledge the Magnus Ehrnrooth Foundation (J. S. W.), the MICIU/AEI of Spain (A. F. project PID2020-115637GB-I00, FEDER), the Academy of Finland (K. R. grant no. 317259), and the University of Jyvaskyla, Finland for financial support. | |
| dc.type.okm | A1 |
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