Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
Ward, J. S., Gomila, R. M., Frontera, A., & Rissanen, K. (2022). Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines. RSC Advances, 12(14), 8674-8682. https://doi.org/10.1039/d2ra01390h
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RSC AdvancesDate
2022Copyright
© 2022 The Author(s). Published by the Royal Society of Chemistry
The silver(I) and iodine(I) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(I) complex formation. The complexes were characterised by 1H and 1H–15N HMBC NMR, X-ray crystallography, and DFT calculations. The solid-state structures for the silver(I) and iodine(I) complexes were extensively compared to the literature and analysed by DFT to examine the influence of the sterically bulky pyridines and their anions.
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Royal Society of Chemistry (RSC)ISSN Search the Publication Forum
2046-2069Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/117399984
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Academy of FinlandFunding program(s)
Academy Project, AoF
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The authors gratefully acknowledge the Magnus Ehrnrooth Foundation (J. S. W.), the MICIU/AEI of Spain (A. F. project PID2020-115637GB-I00, FEDER), the Academy of Finland (K. R. grant no. 317259), and the University of Jyvaskyla, Finland for financial support.License
Except where otherwise noted, this item's license is described as CC BY-NC 3.0