Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
Ward, J. S., Gomila, R. M., Frontera, A., & Rissanen, K. (2022). Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines. RSC Advances, 12(14), 8674-8682. https://doi.org/10.1039/d2ra01390h
Julkaistu sarjassa
RSC AdvancesPäivämäärä
2022Tekijänoikeudet
© 2022 The Author(s). Published by the Royal Society of Chemistry
The silver(I) and iodine(I) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(I) complex formation. The complexes were characterised by 1H and 1H–15N HMBC NMR, X-ray crystallography, and DFT calculations. The solid-state structures for the silver(I) and iodine(I) complexes were extensively compared to the literature and analysed by DFT to examine the influence of the sterically bulky pyridines and their anions.
Julkaisija
Royal Society of Chemistry (RSC)ISSN Hae Julkaisufoorumista
2046-2069Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/117399984
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Suomen AkatemiaRahoitusohjelmat(t)
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The authors gratefully acknowledge the Magnus Ehrnrooth Foundation (J. S. W.), the MICIU/AEI of Spain (A. F. project PID2020-115637GB-I00, FEDER), the Academy of Finland (K. R. grant no. 317259), and the University of Jyvaskyla, Finland for financial support.Lisenssi
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