Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds
Yu, S., Kalenius, E., Frontera, A., & Rissanen, K. (2021). Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds. Chemical Communications, 57(93), 12464-12467. https://doi.org/10.1039/D1CC05616F
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Chemical CommunicationsDate
2021Copyright
© The Royal Society of Chemistry 2021
New 1–2 nm macrocyclic iodine(I) complexes prepared VIA a simple ligand exchange reaction manifest rigid 0.5–1 nm cavities that bind the hexafluorophosphate anion in the gas phase. The size of the cavities and the electrostatic interactions with the iodine(I) cations influence the anion binding properties of these macrocyclic complexes.
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Royal Society of Chemistry (RSC)ISSN Search the Publication Forum
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https://converis.jyu.fi/converis/portal/detail/Publication/102302744
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Research Council of FinlandFunding program(s)
Academy Project, AoFAdditional information about funding
We gratefully acknowledge financial support from the Academy of Finland (K. R. grant no. 317259), the MICIU/AEI of Spain (A. F. project CTQ2017-85821-R FEDER), and the University of Jyvaskyla, Finland.License
Except where otherwise noted, this item's license is described as CC BY-NC 3.0