Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds

Yu, Shilin; Kalenius, Elina; Frontera, Antonio; Rissanen, Kari

doi:10.1039/D1CC05616F

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Yu, S., Kalenius, E., Frontera, A., & Rissanen, K. (2021). Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds. Chemical Communications, 57(93), 12464-12467. https://doi.org/10.1039/D1CC05616F

Julkaistu sarjassa

Chemical Communications

Tekijät

Yu, Shilin |

Kalenius, Elina |

Frontera, Antonio |

Rissanen, Kari

Päivämäärä

2021

Oppiaine

Analyyttinen kemia Orgaaninen kemia Analytical Chemistry Organic Chemistry

Tekijänoikeudet

New 1–2 nm macrocyclic iodine(I) complexes prepared VIA a simple ligand exchange reaction manifest rigid 0.5–1 nm cavities that bind the hexafluorophosphate anion in the gas phase. The size of the cavities and the electrostatic interactions with the iodine(I) cations influence the anion binding properties of these macrocyclic complexes.

Julkaisija

Royal Society of Chemistry (RSC)

ISSN Hae Julkaisufoorumista

1359-7345

Rahoittaja(t)

Suomen Akatemia

Rahoitusohjelmat(t)

Akatemiahanke, SA

Lisätietoja rahoituksesta

We gratefully acknowledge financial support from the Academy of Finland (K. R. grant no. 317259), the MICIU/AEI of Spain (A. F. project CTQ2017-85821-R FEDER), and the University of Jyvaskyla, Finland.

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