dc.contributor.author | Gendy, Chris | |
dc.contributor.author | Rautiainen, J. Mikko | |
dc.contributor.author | Mailman, Aaron | |
dc.contributor.author | Tuononen, Heikki M. | |
dc.date.accessioned | 2021-08-18T07:07:36Z | |
dc.date.available | 2021-08-18T07:07:36Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Gendy, C., Rautiainen, J. M., Mailman, A., & Tuononen, H. M. (2021). Low‐valent Germanylidene Anions : Efficient Single‐site Nucleophiles for Activation of Small Molecules. <i>Chemistry : A European Journal</i>, <i>27</i>(58), 14405-14409. <a href="https://doi.org/10.1002/chem.202102804" target="_blank">https://doi.org/10.1002/chem.202102804</a> | |
dc.identifier.other | CONVID_99340958 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/77419 | |
dc.description.abstract | Rare mononuclear and helical chain low-valent germanylidene anions supported by cyclic (alkyl)(amino) carbene and hypermetallyl ligands were synthesized by stepwise reduction from corresponding germylene precursors via stable acyclic germanium radicals. The germanylidene anions can be described with ylidene and ylidone resonance forms of which the latter becomes prevalent when engaging with electrophiles. Reactions of CO 2 resulted in the formation of μ-CO 2 -κC:κO adducts, a previously uncharacterized coordination mode for low-valent germanium and inaccessible for related neutral ylidones. These results implicate low-valent germanylidene anions as efficient single-site nucleophiles for activation of small molecules. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Wiley | |
dc.relation.ispartofseries | Chemistry : A European Journal | |
dc.rights | CC BY-NC-ND 4.0 | |
dc.subject.other | germanium | |
dc.subject.other | main group elements | |
dc.subject.other | sub-valent compounds | |
dc.subject.other | donor-acceptor systems | |
dc.subject.other | small molecule activation | |
dc.title | Low‐valent Germanylidene Anions : Efficient Single‐site Nucleophiles for Activation of Small Molecules | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202108184582 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 14405-14409 | |
dc.relation.issn | 0947-6539 | |
dc.relation.numberinseries | 58 | |
dc.relation.volume | 27 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 772510 | |
dc.relation.grantnumber | 772510 | |
dc.relation.projectid | info:eu-repo/grantAgreement/EC/H2020/772510/EU//SMAC-MC | |
dc.subject.yso | valenssi (kemia) | |
dc.subject.yso | molekyylit | |
dc.subject.yso | kemialliset reaktiot | |
dc.subject.yso | kemialliset yhdisteet | |
dc.subject.yso | germanium | |
dc.subject.yso | aktivointi | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p6865 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p2984 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p3658 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p324 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p22858 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p17894 | |
dc.rights.url | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.relation.doi | 10.1002/chem.202102804 | |
dc.relation.funder | European Commission | en |
dc.relation.funder | Euroopan komissio | fi |
jyx.fundingprogram | ERC Consolidator Grant | en |
jyx.fundingprogram | ERC Consolidator Grant | fi |
jyx.fundinginformation | Financial support for this work was provided by the University of Jyväskylä. This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (grant agreement #772510 to H.M.T). Computational resources were provided by the Finnish Grid and Cloud Infrastructure (persistent identifier urn:nbn:fi:research-infras-2016072533). | |
dc.type.okm | A1 | |