Show simple item record

dc.contributor.authorYu, Shilin
dc.contributor.authorWard, Jas S.
dc.contributor.authorTruong, Khai-Nghi
dc.contributor.authorRissanen, Kari
dc.contributor.author
dc.date.accessioned2021-07-20T07:38:55Z
dc.date.available2021-07-20T07:38:55Z
dc.date.issued2021
dc.identifier.citationYu, Shilin, Ward, Jas S., Truong, Khai-Nghi, Rissanen, Kari, . (2021). Carbonyl Hypoiodites as Extremely Strong Halogen Bond Donors. <i>Angewandte Chemie</i>, <i>Early online</i>. <a href="https://doi.org/10.1002/anie.202108126" target="_blank">https://doi.org/10.1002/anie.202108126</a>
dc.identifier.otherCONVID_99048332
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/77193
dc.description.abstractNeutral halogen-bonded O−I−N complexes were prepared from in situ formed carbonyl hypoiodites and aromatic organic bases. The carbonyl hypoiodites have a strongly polarized iodine atom with larger σ-holes than any known uncharged halogen bond donor. Modulating the Lewis basicity of the selected pyridine derivatives and carboxylates leads to halogen-bonded complexes where the classical O−I⋅⋅⋅N halogen bond transforms more into a halogen-bonded COO−⋅⋅⋅I−N+ ion-pair (salt) with an asymmetric O−I−N moiety. X-ray analyses, NMR studies, and calculations reveal the halogen bonding geometries of the carbonyl hypoiodite-based O−I−N complexes, confirming that in the solid-state the iodine atom is much closer to the N-atom of the pyridine derivatives than its original position at the carboxylate O-atom.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsCC BY-NC 4.0
dc.titleCarbonyl Hypoiodites as Extremely Strong Halogen Bond Donors
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202107204367
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.relation.issn1433-7851
dc.relation.volumeEarly online
dc.type.versionpublishedVersion
dc.rights.copyright© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber317259
dc.subject.ysosupramolekulaarinen kemia
dc.subject.ysokemialliset sidokset
dc.subject.ysohalogeenit
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p4164
dc.rights.urlhttps://creativecommons.org/licenses/by-nc/4.0/
dc.relation.doi10.1002/anie.202108126
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundinginformationWe are grateful for financial support from the Academy of Finland (K.R.: grant no. 317259), the Finnish Cultural Foundation Central Fund (J.S.W.: grant no. 00201148), the Magnus Ehrnrooth Foundation (J.S.W.), and the University of Jyväskylä.


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

CC BY-NC 4.0
Except where otherwise noted, this item's license is described as CC BY-NC 4.0