Regio‐ and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light
| dc.contributor.author | Shi, Peng | |
| dc.contributor.author | Tu, Yongliang | |
| dc.contributor.author | Zhang, Duo | |
| dc.contributor.author | Wang, Chenyang | |
| dc.contributor.author | Truong, Khai‐Nghi | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Bolm, Carsten | |
| dc.date.accessioned | 2021-03-12T12:21:18Z | |
| dc.date.available | 2021-03-12T12:21:18Z | |
| dc.date.issued | 2021 | |
| dc.identifier.citation | Shi, P., Tu, Y., Zhang, D., Wang, C., Truong, K., Rissanen, K., & Bolm, C. (2021). Regio‐ and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light. <i>Advanced Synthesis and Catalysis</i>, <i>363</i>(10), 2552-2556. <a href="https://doi.org/10.1002/adsc.202100162" target="_blank">https://doi.org/10.1002/adsc.202100162</a> | |
| dc.identifier.other | CONVID_51880182 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/74619 | |
| dc.description.abstract | By visible‐light photoredox catalysis with copper complexes, sulfoximidoyl chlorides add to terminal aryl alkynes to give the corresponding (E)‐β‐chlorovinyl sulfoximines with exclusive regio‐ and stereoselectivities in high yields. Two representative products have been characterized by X‐ray crystal structure analysis. Radicals appear to be decisive intermediates. As demonstrated by two subsequent reactions, the products can be derivatized. | en |
| dc.format.mimetype | application/pdf | |
| dc.language | eng | |
| dc.language.iso | eng | |
| dc.publisher | Wiley | |
| dc.relation.ispartofseries | Advanced Synthesis and Catalysis | |
| dc.rights | CC BY 4.0 | |
| dc.subject.other | alkyne addition | |
| dc.subject.other | copper catalysis | |
| dc.subject.other | difunctionalization | |
| dc.subject.other | vinyl sulfoximine | |
| dc.subject.other | visible-light photoredox catalysis | |
| dc.title | Regio‐ and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202103121962 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Orgaaninen kemia | fi |
| dc.contributor.oppiaine | Organic Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 2552-2556 | |
| dc.relation.issn | 1615-4150 | |
| dc.relation.numberinseries | 10 | |
| dc.relation.volume | 363 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2021 The Authors. Advanced Synthesis & Catalysis published by Wiley-VCH GmbH. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.format.content | fulltext | |
| dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
| dc.relation.doi | 10.1002/adsc.202100162 | |
| jyx.fundinginformation | China Scholarship Council for predoctoral stipends Alexander von Humboldt Foundation. Open access funding enabled and organized by Projekt DEAL. | |
| dc.type.okm | A1 |
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