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dc.contributor.authorPerlepe, Panagiota
dc.contributor.authorOyarzabal, Itziar
dc.contributor.authorMailman, Aaron
dc.contributor.authorYquel, Morgane
dc.contributor.authorPlatunov, Mikhail
dc.contributor.authorDovgaliuk, Iurii
dc.contributor.authorRouzières, Mathieu
dc.contributor.authorNégrier, Philippe
dc.contributor.authorMondieig, Denise
dc.contributor.authorSuturina, Elizaveta A.
dc.contributor.authorDourges, Marie-Anne
dc.contributor.authorBonhommeau, Sébastien
dc.contributor.authorMusgrave, Rebecca A.
dc.contributor.authorPedersen, Kasper S.
dc.contributor.authorChernyshov, Dmitry
dc.contributor.authorWilhelm, Fabrice
dc.contributor.authorRogalev, Andrei
dc.contributor.authorMathonière, Corine
dc.contributor.authorClérac, Rodolphe
dc.date.accessioned2021-02-08T12:28:44Z
dc.date.available2021-02-08T12:28:44Z
dc.date.issued2020
dc.identifier.citationPerlepe, P., Oyarzabal, I., Mailman, A., Yquel, M., Platunov, M., Dovgaliuk, I., Rouzières, M., Négrier, P., Mondieig, D., Suturina, E. A., Dourges, M.-A., Bonhommeau, S., Musgrave, R. A., Pedersen, K. S., Chernyshov, D., Wilhelm, F., Rogalev, A., Mathonière, C., & Clérac, R. (2020). Metal-organic magnets with large coercivity and ordering temperatures up to 242°C. <i>Science</i>, <i>370</i>(6516), 587-592. <a href="https://doi.org/10.1126/science.abb3861" target="_blank">https://doi.org/10.1126/science.abb3861</a>
dc.identifier.otherCONVID_43466478
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/74029
dc.description.abstractMagnets derived from inorganic materials (e.g., oxides, rare-earth–based, and intermetallic compounds) are key components of modern technological applications. Despite considerable success in a broad range of applications, these inorganic magnets suffer several drawbacks, including energetically expensive fabrication, limited availability of certain constituent elements, high density, and poor scope for chemical tunability. A promising design strategy for next-generation magnets relies on the versatile coordination chemistry of abundant metal ions and inexpensive organic ligands. Following this approach, we report the general, simple, and efficient synthesis of lightweight, molecule-based magnets by postsynthetic reduction of preassembled coordination networks that incorporate chromium metal ions and pyrazine building blocks. The resulting metal-organic ferrimagnets feature critical temperatures up to 242°C and a 7500-oersted room-temperature coercivityen
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherAmerican Association for the Advancement of Science (AAAS)
dc.relation.ispartofseriesScience
dc.rightsIn Copyright
dc.subject.othermetal-organic magnets
dc.subject.otherlarge coercivity
dc.subject.otherordering temperatures
dc.titleMetal-organic magnets with large coercivity and ordering temperatures up to 242°C
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202102081470
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineInorganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange587-592
dc.relation.issn0036-8075
dc.relation.numberinseries6516
dc.relation.volume370
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 the Authors
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber289172
dc.subject.ysolämpötila
dc.subject.ysomagneetit
dc.subject.ysoorganometalliyhdisteet
dc.subject.ysomagneettiset ominaisuudet
dc.subject.ysokiteet
dc.subject.ysokompleksiyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p2100
jyx.subject.urihttp://www.yso.fi/onto/yso/p2774
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
jyx.subject.urihttp://www.yso.fi/onto/yso/p597
jyx.subject.urihttp://www.yso.fi/onto/yso/p15440
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1126/science.abb3861
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundinginformationThis work was supported by the University of Bordeaux, the Région Nouvelle Aquitaine, Quantum Matter Bordeaux, and the Centre National de la Recherche Scientifique (CNRS). I.O. and R.C. are grateful to the Basque Government for I.O.'s postdoctoral grant. K.S.P. thanks the VILLUM FONDEN for a Villum Young Investigator grant (15374). A.M. thanks JYU and the Academy of Finland (project 289172) for support.


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