dc.contributor.author | Queen, Joshua D. | |
dc.contributor.author | Lehmann, Annika | |
dc.contributor.author | Fettinger, James C. | |
dc.contributor.author | Tuononen, Heikki M. | |
dc.contributor.author | Power, Philip P. | |
dc.date.accessioned | 2020-12-22T10:27:57Z | |
dc.date.available | 2020-12-22T10:27:57Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Queen, J. D., Lehmann, A., Fettinger, J. C., Tuononen, H. M., & Power, P. P. (2020). The Monomeric Alanediyl : AlAriPr8 (AriPr8 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2) : An Organoaluminum(I) Compound with a One-Coordinate Aluminum Atom. <i>Journal of the American Chemical Society</i>, <i>142</i>(49), 20554-20559. <a href="https://doi.org/10.1021/jacs.0c10222" target="_blank">https://doi.org/10.1021/jacs.0c10222</a> | |
dc.identifier.other | CONVID_47122199 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/73393 | |
dc.description.abstract | Reduction of the aluminum iodide AlI2AriPr8 (1; AriPr8 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2) with 5% w/w Na/NaCl in hexanes gave a dark red solution from which the monomeric alanediyl :AlAriPr8 (2) was isolated in ca. 28% yield as yellow-orange crystals. Compounds 1 and 2 were characterized by X-ray crystallography, electronic and NMR spectroscopy, and theoretical calculations. The Al atom in 2 is one-coordinate, and the compound displays two absorptions in its electronic spectrum at 354 and 455 nm. It reacts with H2 under ambient conditions to give the aluminum hydride {AlH(μ-H)AriPr8}2, probably via a weakly bound dimer of 2 as an intermediate. | en |
dc.format.mimetype | application/pdf | |
dc.language | eng | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society (ACS) | |
dc.relation.ispartofseries | Journal of the American Chemical Society | |
dc.rights | CC BY-NC-ND 4.0 | |
dc.title | The Monomeric Alanediyl : AlAriPr8 (AriPr8 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2) : An Organoaluminum(I) Compound with a One-Coordinate Aluminum Atom | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202012227335 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 20554-20559 | |
dc.relation.issn | 0002-7863 | |
dc.relation.numberinseries | 49 | |
dc.relation.volume | 142 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © 2020 American Chemical Society | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 772510 | |
dc.relation.grantnumber | 772510 | |
dc.relation.projectid | info:eu-repo/grantAgreement/EC/H2020/772510/EU//SMAC-MC | |
dc.subject.yso | alumiini | |
dc.subject.yso | organometalliyhdisteet | |
dc.subject.yso | kompleksiyhdisteet | |
dc.subject.yso | kemiallinen synteesi | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p19563 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p28123 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p8468 | |
dc.rights.url | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.relation.doi | 10.1021/jacs.0c10222 | |
dc.relation.funder | European Commission | en |
dc.relation.funder | Euroopan komissio | fi |
jyx.fundingprogram | ERC Consolidator Grant | en |
jyx.fundingprogram | ERC Consolidator Grant | fi |
jyx.fundinginformation | This project received funding from the European Research Council under the European Union’s Horizon 2020 research and innovation programme (Grant No. 772510 to H.M.T.). | |
dc.type.okm | A1 | |