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dc.contributor.authorvon der Heiden, Daniel
dc.contributor.authorRissanen, Kari
dc.contributor.authorErdélyi, Máté
dc.date.accessioned2020-11-26T12:29:37Z
dc.date.available2020-11-26T12:29:37Z
dc.date.issued2020
dc.identifier.citationvon der Heiden, D., Rissanen, K., & Erdélyi, M. (2020). Asymmetric [N–I–N]+ halonium complexes in solution?. <i>Chemical Communications</i>, <i>56</i>(92), 14431-14434. <a href="https://doi.org/10.1039/D0CC06706G" target="_blank">https://doi.org/10.1039/D0CC06706G</a>
dc.identifier.otherCONVID_47125567
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/72833
dc.description.abstractAssessment of the solution equilibria of [bis(pyridine)iodine(I)]+ complexes by ESI-MS and NMR reveals the preference of iodine(I) to form complexes with a more basic pyridine. Mixtures of symmetric [bis(pyridine)iodine(I)]+ complexes undergo statistical ligand exchange, with a predominant entropic driving force favoring asymmetric systems. The influence of ligand basicity, concentration, temperature, and ligand composition is evaluated. Our findings are expected to facilitate the investigations, and the supramolecular and synthetic applications of halonium ions’ halogen bonds.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesChemical Communications
dc.rightsCC BY 4.0
dc.titleAsymmetric [N–I–N]+ halonium complexes in solution?
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202011266799
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange14431-14434
dc.relation.issn1359-7345
dc.relation.numberinseries92
dc.relation.volume56
dc.type.versionpublishedVersion
dc.rights.copyright© The Royal Society of Chemistry 2020
dc.rights.accesslevelopenAccessfi
dc.subject.ysoliuokset
dc.subject.ysojodi
dc.subject.ysoligandit
dc.subject.ysokompleksiyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p4335
jyx.subject.urihttp://www.yso.fi/onto/yso/p18902
jyx.subject.urihttp://www.yso.fi/onto/yso/p24741
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1039/D0CC06706G
jyx.fundinginformationThis project made use of the NMR Uppsala infrastructure, which is funded by the Department of Chemistry – BMC and the Disciplinary Domain of Medicine and Pharmacy, and was supported by Vinnova [2019-02160], FORMAS [2017-0009] and the Swedish Research Council [2016-03602].


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