Asymmetric [N–I–N]+ halonium complexes
Ward, J. S., Fiorini, G., Frontera, A., & Rissanen, K. (2020). Asymmetric [N–I–N]+ halonium complexes. Chemical Communications, 56(60), 8428-8431. https://doi.org/10.1039/d0cc02758h
Published inChemical Communications
© The Royal Society of Chemistry 2020
The first asymmetric halogen-bonded iodonium complexes [I(py)(4-DMAP)]PF6 (2c) and [I(py)(4-Etpy)]PF6 (2e) were prepared via [N-Ag-N]+ → [N-I-N]+ cation exchange of their analogous 2-coordinate silver complexes. The complexes were characterised by 1H and 1H-15N HMBC NMR spectroscopy, and single crystal X-ray crystallography.
PublisherRoyal Society of Chemistry
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Additional information about fundingFinancial support by MICIU/AEI of Spain (AF, project number CTQ2017-85821-R, FEDER funds) and The Finnish Cultural Foundation Central Fund (JSW, grant number 00201148) is gratefully acknowledged.
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