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dc.contributor.authorChernysheva, Maria V.
dc.contributor.authorHaukka, Matti
dc.date.accessioned2020-10-19T08:28:34Z
dc.date.available2020-10-19T08:28:34Z
dc.date.issued2021
dc.identifier.citationChernysheva, M. V., & Haukka, M. (2021). The S … Hal and Se … Hal chalcogen bonding in a series of thiourea, selenourea and their derivatives. <i>Journal of Solid State Chemistry</i>, <i>293</i>, Article 121759. <a href="https://doi.org/10.1016/j.jssc.2020.121759" target="_blank">https://doi.org/10.1016/j.jssc.2020.121759</a>
dc.identifier.otherCONVID_42545325
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/72236
dc.description.abstractThe chalcogen bonding (ChB) in a series of thiourea, selenourea and their derivatives has been investigated in the present paper. Thus, selenourea and dimethylselenourea undergo dimerization and trimerization processes in the presence of various halogen species (1–5). Selenourea and dimethylselenourea form trimers 3–4 in the presence of lighter halogens (chlorine and bromine) through Se⋯Se chalcogen bonding. When moving to heavier halogen (iodine), the dimers 1–2 are formed. Thiourea and its derivatives also tend to make very strong S⋯S bonds and form dimers in the case of lighter halogens chlorine and bromine (compounds 6–7). However, the monomers separated by the iodine species are formed upon interaction with iodine via very strong S⋯I bonding (compounds 9–12). Furthermore, among all the crystal structures of 1–12, only iodine cations I+ in 10 and 12 act as electron density acceptors, while in the remaining compounds 1–9 and 11 halogen species act as electron density donors.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherElsevier BV
dc.relation.ispartofseriesJournal of Solid State Chemistry
dc.rightsIn Copyright
dc.subject.otherchalcogen bonding
dc.subject.otherhalogen
dc.subject.otherselenourea
dc.subject.otherthiourea
dc.titleThe S … Hal and Se … Hal chalcogen bonding in a series of thiourea, selenourea and their derivatives
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202010196295
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineInorganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.relation.issn0022-4596
dc.relation.volume293
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 Elsevier
dc.rights.accesslevelopenAccessfi
dc.subject.ysojodi
dc.subject.ysohalogeenit
dc.subject.ysokemialliset sidokset
dc.subject.ysobromi
dc.subject.ysokloori
dc.subject.ysokemia
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p18902
jyx.subject.urihttp://www.yso.fi/onto/yso/p4164
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
jyx.subject.urihttp://www.yso.fi/onto/yso/p7981
jyx.subject.urihttp://www.yso.fi/onto/yso/p12904
jyx.subject.urihttp://www.yso.fi/onto/yso/p1801
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1016/j.jssc.2020.121759


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