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Non-conventional synthesis and photophysical studies of platinum(II) complexes with methylene bridged 2,2′-dipyridylamine derivatives
Bulatov, Evgeny; Haukka, Matti (Royal Society of Chemistry, 2019)Methylene bridged 2,2′-dipyridylamine (dpa) derivatives and their metal complexes possess outstanding properties due to their inherent structural flexibility. Synthesis of such complexes typically involves derivatization ... -
Cytotoxicity and Apoptosis-Induction in MCF-7 Cells for New Pd(II) Complex Based on s-Triazine Ligand : Synthesis, Single Crystal X-ray Diffraction Analysis and Structural Investigations
Alayyaf, Abdulmajeed Abdullah; Barakat, Assem; Al-Majid, Abdullah Mohammed; Ali, M.; Yousuf, Sammer; Haukka, Matti; El-Faham, Ayman; Soliman, Saied M.; Nafie, Mohamed S. (MDPI AG, 2023)The synthesis and X-ray structure analysis of the new [PdLCl2]*0.5 CH2Cl2 complex where L is hydrazono-s-triazine di-morpholine derivative, were presented. In the neutral inner sphere of this complex, the organic ligand L ... -
Molybdenum(VI) complexes with a chiral L-alanine bisphenol [O,N,O,O’] ligand : Synthesis, structure, spectroscopic properties and catalytic activity
Peuronen, Anssi; Kivelä, Henri; Salonen, Pasi; Eskonen, Ville; Karman, Marta; Lahtinen, Manu; Romanowski, Grzegorz; Lehtonen, Ari (Elsevier BV, 2023)Dioxidomolybdenum(VI) compound [MoO2Cl2(dmso)2] reacts with a chiral tetradentate O3N-type L-alanine bisphenol ligand precursor (Et3NH)H2Lala to form an oxidochloridomolybdenum(VI) complex [MoOCl(Lala)] (1) as two separable ... -
Discovery of Potent Indolyl-Hydrazones as Kinase Inhibitors for Breast Cancer : Synthesis, X-ray Single-Crystal Analysis, and In Vitro and In Vivo Anti-Cancer Activity Evaluation
Salama, Eid E.; Youssef, Mohamed F.; Aboelmagd, Ahmed; Boraei, Ahmed T. A.; Nafie, Mohamed S.; Haukka, Matti; Barakat, Assem; Sarhan, Ahmed A. M. (MDPI AG, 2023)According to data provided by the World Health Organization (WHO), a total of 2.3 million women across the globe received a diagnosis of breast cancer in the year 2020, and among these cases, 685,000 resulted in fatalities. ... -
PtII versus PdII-assisted [2+3] cycloadditions of nitriles and nitrone. Synthesis of nitrile-derived arylamido platinum(II) and Δ4-1,2,4-oxadiazoline palladium(II) complexes
Lasri, Jamal; Eltayeb, Naser Eltaher; Haukka, Matti; Babgi, Bandar A. (Pergamon Press, 2019)The reactions of bis(organonitrile) platinum(II) complexes trans-[PtCl2(NCR)2] (R = C6H4(p-HCO), CH2C6H4(p-CH3)) with pyrroline N-oxide −O+NCHCH2CH2CMe2 afford arylamido platinum(II) complexes trans-[PtCl2{(OCR)NCCH2CH2CMe2NH}2] ...