dc.contributor.author | Zhou, Xueer | |
dc.contributor.author | Vasko, Petra | |
dc.contributor.author | Hicks, Jamie | |
dc.contributor.author | Fuentes, M. Angeles | |
dc.contributor.author | Heilmann, Andreas | |
dc.contributor.author | Kolychev, Eugene L. | |
dc.contributor.author | Aldridge, Simon | |
dc.date.accessioned | 2020-07-07T05:41:56Z | |
dc.date.available | 2020-07-07T05:41:56Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Zhou, X., Vasko, P., Hicks, J., Fuentes, M. A., Heilmann, A., Kolychev, E. L., & Aldridge, S. (2020). Cooperative N–H bond activation by amido-Ge(ii) cations. <i>Dalton Transactions</i>, <i>49</i>(27), 9495-9504. <a href="https://doi.org/10.1039/d0dt01960g" target="_blank">https://doi.org/10.1039/d0dt01960g</a> | |
dc.identifier.other | CONVID_41511997 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/71088 | |
dc.description.abstract | N-heterocyclic carbene (NHC) and tertiary phosphine-stabilized germylium-ylidene cations, [R(L)Ge:]+, featuring tethered amido substituents at R have been synthesized via halide abstraction. Characterization in the solid state by X-ray crystallography shows these systems to be monomeric, featuring a two-coordinate C,N- or P,N-ligated germanium atom. The presence of the strongly Lewis acidic cationic germanium centre and proximal amide function allows for facile cleavage of N–H bonds in 1,2-fashion: the products resulting from reactions with carbazole feature a tethered secondary amine donor bound to a three-coordinate carbazolyl-GeII centre. In each case, addition of the components of the N–H bond occurs to the same face of the germanium amide function, consistent with a coordination/proton migration mechanism. Such as sequence is compatible with the idea that substrate coordination via the pπ orbital at germanium reduces the extent of N-to-Ge π donation from the amide, thereby enhancing the basicity of the proximal N-group. | en |
dc.format.mimetype | application/pdf | |
dc.language | eng | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.relation.ispartofseries | Dalton Transactions | |
dc.rights | CC BY 4.0 | |
dc.title | Cooperative N–H bond activation by amido-Ge(ii) cations | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202007075261 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 9495-9504 | |
dc.relation.issn | 1477-9226 | |
dc.relation.numberinseries | 27 | |
dc.relation.volume | 49 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © The Royal Society of Chemistry 2020 | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 314794 | |
dc.subject.yso | kemialliset sidokset | |
dc.subject.yso | germanium | |
dc.subject.yso | kompleksiyhdisteet | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p10130 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p22858 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
dc.relation.doi | 10.1039/d0dt01960g | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Suomen Akatemia | fi |
jyx.fundingprogram | Postdoctoral Researcher, AoF | en |
jyx.fundingprogram | Tutkijatohtori, SA | fi |
jyx.fundinginformation | We acknowledge funding from the Academy of Finland (project number 314794, PV), the Oxford-SCG Centre of Excellence and the Leverhulme Trust (grant number RP-2018-246, JH), the EPSRC (grant number EP/K014714/1, MAF) and the EU 7th Framework Program, Marie Skłodowska-Curie actions (grant number PIEF-GA-2013-626441 for an IEF Fellowship, EK). | |
dc.type.okm | A1 | |