dc.contributor.author | Hicks, Jamie | |
dc.contributor.author | Vasko, Petra | |
dc.contributor.author | Goicoechea, Jose M. | |
dc.contributor.author | Aldridge, Simon | |
dc.date.accessioned | 2020-06-24T13:18:39Z | |
dc.date.available | 2020-06-24T13:18:39Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Hicks, J., Vasko, P., Goicoechea, J. M., & Aldridge, S. (2021). The Aluminyl Anion : A New Generation of Aluminium Nucleophile. <i>Angewandte Chemie</i>, <i>60</i>(4), 1702-1713. <a href="https://doi.org/10.1002/anie.202007530" target="_blank">https://doi.org/10.1002/anie.202007530</a> | |
dc.identifier.other | CONVID_36028313 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/70782 | |
dc.description.abstract | Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and laboratory-based reactions. Recently, a series of isolable aluminium(I) anions ('aluminyls') have been reported, which offer an alternative to this textbook description: these reagents behave as aluminium nucleophiles. This minireview covers the synthesis, structure and reactivity of aluminyl species reported to date, together with their associated metal complexes. The frontier orbitals of each of these species have been investigated using a common methodology to allow for a like-for-like comparison of their electronic structure and a means of rationalising (sometimes unprecedented) patterns of reactivity. | en |
dc.format.mimetype | application/pdf | |
dc.language | eng | |
dc.language.iso | eng | |
dc.publisher | Wiley-VCH Verlag | |
dc.relation.ispartofseries | Angewandte Chemie | |
dc.rights | In Copyright | |
dc.subject.other | alumiiniyhdisteet | |
dc.subject.other | aluminyl | |
dc.subject.other | aluminium | |
dc.subject.other | nucleophile organometallic | |
dc.subject.other | main group | |
dc.title | The Aluminyl Anion : A New Generation of Aluminium Nucleophile | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202006244972 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_dcae04bc | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 1702-1713 | |
dc.relation.issn | 1433-7851 | |
dc.relation.numberinseries | 4 | |
dc.relation.volume | 60 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2020 WILEY | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 314794 | |
dc.subject.yso | reaktiivisuus | |
dc.subject.yso | alumiini | |
dc.subject.yso | kompleksiyhdisteet | |
dc.subject.yso | organometalliyhdisteet | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p19397 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p19563 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p28123 | |
dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
dc.relation.doi | 10.1002/anie.202007530 | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Suomen Akatemia | fi |
jyx.fundingprogram | Postdoctoral Researcher, AoF | en |
jyx.fundingprogram | Tutkijatohtori, SA | fi |
jyx.fundinginformation | JH would like to thank the Australian Research Council and the Australian Government for funding aspects of this work (DE190100524). PV thanks the Academy of Finland (Grant No. 314794) and Prof. Heikki M. Tuononen for continued support and computational resources. JMG and SA would also like to thank the Leverhulme Trust (F/08699/E) for funding aspects of this work. | |
dc.type.okm | A2 | |